Skip to main content
SpringerLink
Log in

Substitutions of organopalladium(II) species with benzimidazole derivatives

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The [Pd(cod)(cotl)]ClO4 complex (cod = cycloocta-1,5-diene; cotl = cyclooctenyl, C18H13 −) undergoes substitutions with new Schiff base ligands containing benzimidazole L [L = 2-(2′-N-n-propylidenephenyl)benzimidazole (L1); 2-(2′-N-i-propylidenephenyl)benzimidazole (L2); 2-(2′-N-n-butylidenephenyl)benzimidazole (L3); 2-(2′-N-i-butylidenephenyl)benzimidazole (L4)]. Facile displacement of cod by L occurs to produce complexes of the type [Pd(cotl)L]ClO4· nMe2CO (n= 0; L = L1, L2 or L3; n= 2, L = L4). Dihalobridge complexes of the type [Pd(cotl)X]2(X = Cl or Br) undergo halogen-bridge cleavage with L1–L4 to give mononuclear complexes of the type Pd(cotl)LX · nH2O (n= 2, X = Cl, L = L1; n= 0, X = Br, L = L1; n= 0, X = Cl, L = L2; n= 0, X = Cl or Br, L = L3; n= 0, X = Cl, L = L4; n= 2, X = Br, L = L4) and a binuclear complex [Pd(cotl)Br]2L2. The complexes were characterised by physical properties, i.r., 1H- and 13C-n.m.r. spectral techniques and by mass spectra. Probable structures have been proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. Ramdehul, L. Barloy and J.A. Osborn, Organometallics, 15, 5442 (1996).

    Article  Google Scholar 

  2. J. Elguero, A. Fruchier, A. Hoz, F.A. Jalon, B.R. Manzano, A. Otero and F.G. Torre, Chem. Ber., 129, 589 (1996).

    Google Scholar 

  3. G. Consiglio and R.M. Waymounth, Chem. Rev., 89, 257 (1989).

    Google Scholar 

  4. P.R. Auburn, P.B. Mackenzie and B. Bosnich, J. Am. Chem. Soc., 107, 2033 (1985).

    Google Scholar 

  5. D.J. Farrar and N.C. Payne, J. Am. Chem. Soc., 107, 2054 (1985).

    Google Scholar 

  6. T. Benincori, E. Brenna, F. Sannicolo, L. Trimarco, P. Antognaza, E. Cesarolti, F. Dermartin and T.P.G. Zolti, J. Organometal Chem., 529, 445 (1997).

    Article  Google Scholar 

  7. Y. Tung, W. Tseng, C. Lee, P. Hsu, Y. Chi, S. Peng and G. Lee, Organometallics, 18, 864 (1999).

    Article  Google Scholar 

  8. K. Selvakumar and S. Vancheesan, Polyhedron, 14, 2091 (1995).

    Article  Google Scholar 

  9. P. Souza, M.T. Paz-Andrade and G. Pileher, Thermochim. Acta, 190, 203 (1991).

    Article  Google Scholar 

  10. C. Molleda, J.R. Masuguer and J.A. Garcia Vazquez, Synth. React. Inorg. Met. Org. Chem., 19, 181 (1989).

    Google Scholar 

  11. A. Albinati, C. Arz and P.S. Pregosin, J. Organometal Chem., 356, 367 (1988).

    Article  Google Scholar 

  12. K.R. Nagasundara, N.M. Nanje Gowda and G.K.N. Reddy, Ind. J. Chem., 19A, 1194 (1980).

    Google Scholar 

  13. D.W. Hein, R.I. Alhurn and J. Liquitt, J. Am. Chem. Soc., 79, 427 (1957).

    Google Scholar 

  14. L. Mishra and A. Jha, Ind. J. Chem., 33A, 638 (1994).

    Google Scholar 

  15. L. Mishra and V.K. Singh, Ind. J. Chem., 32A, 446 (1993).

    Google Scholar 

  16. P. Amudha, P Akilan and M. Kandaswamy, Polyhedron, 18, 1355 (1999).

    Article  Google Scholar 

  17. K.J. Morgan, J. Chem. Soc. A, 2343 (1961).

  18. T.J. Lane, I. Nakagawa, J.L. Walter and A.K. Kandathil, Inorg. Chem., 1, 267 (1962)

    Google Scholar 

  19. D.J. Rabiger and M.M. Joullie, J. Org. Chem., 29, 476 (1964).

    Google Scholar 

  20. M.M. Cordes and J.L. Walter, Spectrochim. Acta, 24A, 1421 (1968).

    Article  Google Scholar 

  21. R.S. Srivastava, Ind. J. Chem., 29A, 1024 (1990).

    Google Scholar 

  22. N.M.N. Gowda, SB. Naikar and G.K.N. Reddy, Adv. Inorg. Chem. Radiochem., 28, 255 (1984).

    Google Scholar 

  23. E. Bermejo, R. Carbello, A. Castineiras, A. Lombao, W. Hitler and J. Stralhe, Polyhedron, 10, 1579 (1991).

    Article  Google Scholar 

  24. X. Xiamoming, M. Haga, T. Inoue, Y. Ru, A.W. Addison and K. Kano, J. Chem. Soc., Dalton Trans., 2477 (1993).

  25. V. Gayathri, E.G. Leelamani, N.M.N. Gowda and G.K.N. Reddy, Polyhedron, 18, 2351 (1999).

    Article  Google Scholar 

  26. V. Gayathri, E.G. Leelamani, N.M.N. Gowda and G.K.N. Reddy, Polyhedron, 16, 7 (1997).

    Article  Google Scholar 

  27. G. Orellana, C.A. Ibarra and J. Santoro, Inorg. Chem., 27, 1025 (1988).

    Google Scholar 

  28. F.R. Hartley, J. Organometal Chem., 21, 227 (1970).

    Article  Google Scholar 

  29. R.M. Silverstein, G.C. Bassler and T.C. Morril, Spectrometric Identification of Organic Compounds, 4th edit., Wiley 1981.

  30. C. Senoff, Inorg. Chem., 17, 2320 (1978).

    Google Scholar 

  31. V.D. Felice, V.G. Albano, C. Castellari, M.E. Cucciolite and A. De Renzi, J. Organomet. Chem., 403, 269 (1991).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Central College Campus, Bangalore University, Bangalore, 560 001, India

    Rita Bhattacharjee, Virupaiah Gayathri & Nadur M.N. Gowda

Authors
  1. Rita Bhattacharjee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Virupaiah Gayathri
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nadur M.N. Gowda
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bhattacharjee, R., Gayathri, V. & Gowda, N.M. Substitutions of organopalladium(II) species with benzimidazole derivatives. Transition Metal Chemistry 29, 320–328 (2004). https://doi.org/10.1023/B:TMCH.0000020376.61402.91

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:TMCH.0000020376.61402.91

Keywords

Search

Navigation