Abstract
Two-phase flow and capillarity phenomenon in porous solids, well known in physics and engineering, are treated from a rigorous continuum thermomechanical point of view for the first time. A ternary model, consisting of a porous solid phase, a liquid phase, and a gas phase, is investigated within the framework of thermodynamics. The main result of the evaluation of the entropy principle turns out to be that the interaction forces between the solid, gas, and liquid phases are dependent on the free Helmholtz energy functions of the corresponding phases and on the gradient of the liquid density. The classical result for the driving volume force for raising a water column in a narrow tube against the force of gravity is contained in the general investigation.
Similar content being viewed by others
References
Avraam, D. G. and Payatakes, A. C.: 1999, Flow mechanisms, relative permeabilities and coupling effects in steady-state two-phase flows through porous media. The case of strong wettability, Ind. Eng. Chem. Res. 38, 778–786.
Davis, H. T.: 1996, Statistical Mechanics of Phases, Interfaces, and Thin Films, VCH, New York, Weinheim, Cambridge.
de Boer, R.: 2000, Theory of Porous Media: Highlights in the Historical Development and Current State, Springer, Berlin, Heidelberg, New York.
de Boer, R. and Didwania, A. K.: 1997, The effect of uplift in liquid-saturated porous solids - Karl Terzaghi's contributions and recent findings, Géotechnique 47, 289–298.
de Boer, R. and Didwania, A. K.: 2001, Saturated elastic porous solids: incompressible, compressible, and hybrid binary models, Transport in Porous Media 45, 425–445.
de Boer, R. and Didwania, A. K.: 2002, Capillarity in porous solids: contributions of the Vienna school and recent findings, Acta Mech. 159, 173–188.
Didwania, A. K. and de Boer, R.: New governing equations for immiscible two-phase flow through porous media and their special forms for different applications (in preparation).
Fillunger, P.: 1934, Der Kapillardruck in Talsperren, Wasserwirtschaft 27, 13/14.
Gray, W. G. and Hassanizadeh, S. M.: 1990, Mechanics and thermodynamics of multiphase flow in porous media including interphase boundaries, Adv. Water Resour. 13, 169–186.
Hassanizadeh, S. M. and Gray, W. G.: 1993, Thermodynamic basis of capillary pressure in porous media, Water Resour. Res. 29, 3389–3405.
Kozeny, J.: 1927, Ñber kapillare Leitung des Wassers im Boden (Aufstieg, Versickerung und Anwendung auf die Bewässerung). Sitzungsberichte der Akademie der Wissenschaften in Wien, mathematisch-naturwissenschaftliche Klasse, Abteilung IIa 136, pp. 271–309.
Künzel, H. M.: 1994, Verfahren zur ein-und zweidimensionalen Berechnung des gekoppelten Wärme und Feuchtetransports in Bauteilen mit einfachen Kennwerten, Dissertation, Lehrstuhl für Konstruktive Bauphysik, Fakultät Bauingenieur-und Vermessungswesen der Universität Stuttgart.
Müller, I.: 1994, Grundzüge der Thermodynamik mit Historischen Anmerkungen, Springer, Berlin, Heidelberg, New York.
Muskat, M.: 1937, The Flow of Homogeneous Fluids through Porous Media, McGraw-Hill, New York.
Ricken, T.: 2002, Kapillarität in porösen Medien - theoretische Untersuchungen und numerische Simulation, Dissertation, Institut für Mechanik, Fachbereich 10 - Bauwesen, Universität Essen.
von Terzaghi, K.: 1925, Erdbaumechanik auf bodenphysikalischer Grundlage, Franz Deuticke, Leipzig/Wien.
von Terzaghi, K.: 1933, Auftrieb und Kapillardruck an betonierten Talsperren, Wasserwirtschaft 26, 397–399.
Whitaker, S.: 1986, Flow in porous media. 2. The governing equations for immiscible two-phase flow, Transp. Porous Media 1, 105–125.
Wooding, R. A. and Morel-Seytoux, H. J.: 1976, Multiphase Fluid flow through porous media, in: M. van Dyke, W. G. Vincenti and J. V. Wehausen (eds), Annual Review of Fluid Mechanics Vol. 8, Annual Reviews Inc., Palo Alto, CA, USA.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
de Boer, R., Didwania, A.K. Two-Phase Flow and the Capillarity Phenomenon in Porous Solids – A Continuum Thermomechanical Approach. Transport in Porous Media 56, 137–170 (2004). https://doi.org/10.1023/B:TIPM.0000021731.14083.7f
Issue Date:
DOI: https://doi.org/10.1023/B:TIPM.0000021731.14083.7f