Abstract
We have studied the kinetics of decomposition and reduction of peroxynitrous acid HOONO by cyclohexane in aqueous solutions. We used the measured effective rate constants of the reactions to compare the reactivities of the acid in the processes of isomerization, decomposition, and reduction.
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REFERENCES
J. S. Beckman, Nitric Oxide. Principles and Actions, J. Lancaster, Jr. (ed.), Academic Press, San Diego (1996), pp. 1-82.
G. V. Shustov, R. Spinney, and A. Rauk, J. Am. Chem. Soc., 122, No. 6, 1191-1199 (2000).
J. S. Radi, J. S. Beckman, K. M. Bush, and B. A. Freeman, Arch. Biochem. Biophys., 288, No. 2, 481-487 (1991).
V. L. Lobachev and E. S. Rudakov, Kinet. Katal., 41, No. 2, 208-217 (2000).
V. L. Lobachev, S. L. Kluger, G. P. Zimtseva, et al., Teor. Éksp. Khim., 39, No. 1, 36-39 (2003).
M. Anbar and H. Taube, J. Am. Chem. Soc., 76, No. 24, 6243-6247 (1954).
A. Saha, S. Goldstein, D. Cabelli, and G. Czapski, Free Radical Biol. Med., 24, No. 4, 653-659 (1998).
R. Kissner, T. Nauser, P. Bugnon, et al., Chem. Res. Toxicol., 10, No. 11, 1285-1292 (1997).
J. W. Coddington, J. K. Hurst, and S. V. Lymar, J. Am. Chem. Soc., 121, No. 11, 2438-2443 (1999).
R. Kissner and W. H. Koppenol, J. Am. Chem. Soc., 124, 234-239 (2002).
V. P. Tret'yakov, L. A. Min'ko, E. S. Rudakov, and T. A. Alekhina, Teor. Éksp. Khim., 39, No. 1, 32-35 (2003).
E. S. Rudakov, Reactions of Alkanes with Oxidizing Agents, Metal Complexes, and Radicals in Solutions [in Russian], Nauk. Dumka, Kiev (1985).
I. T. Goronovskii, Yu. P. Nazarenko, and E. F. Nekryach, Concise Chemistry Handbook [in Russian], Nauk. Dumka, Kiev (1974).
V. P. Tret'yakov, Teor. Éksp. Khim., 40, No. 3, 192-195 (2004).
R. Kissner, T. Nauser, C. Kurs, and W. H. Koppenol, IUBMB Life, 55, No. 10/11, 567-572 (2003).
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Tret'yakov, V.P., Min'ko, L.A. & Rudakov, E.S. Kinetics of Conversions of Peroxynitrous Acid in Reactions of Isomerization, Decomposition, and Reduction by Cyclohexane. Theoretical and Experimental Chemistry 40, 309–313 (2004). https://doi.org/10.1023/B:THEC.0000049077.65698.7c
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DOI: https://doi.org/10.1023/B:THEC.0000049077.65698.7c