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Kinetic Model of the PTC Aminolysis of 4-Nitrophenyl Acetate with Solid Potassium Glycinate

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Abstract

A mechanism of phase-transfer catalysis in a solid/liquid system was proposed during akinetic investigation of the aminolysis of 4-nitrophenyl acetate with solid potassium glycinate in chlorobenzene in the presence of 18-crown-6. The quantitative parameters were determined for all the stages of the catalytic cycle, including the distribution of the reagents between the phases and the chemical reactions that occur.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114, Donets'k, Ukraine

    L. N. Vakhitova, V. A. Savelova, Ya. F. Burdina, I. A. Belousova & A. F. Popov

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  1. L. N. Vakhitova
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  2. V. A. Savelova
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  3. Ya. F. Burdina
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  4. I. A. Belousova
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  5. A. F. Popov
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Vakhitova, L.N., Savelova, V.A., Burdina, Y.F. et al. Kinetic Model of the PTC Aminolysis of 4-Nitrophenyl Acetate with Solid Potassium Glycinate. Theoretical and Experimental Chemistry 40, 293–299 (2004). https://doi.org/10.1023/B:THEC.0000049075.69544.da

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  • DOI: https://doi.org/10.1023/B:THEC.0000049075.69544.da

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