Skip to main content
SpringerLink
Log in

Effect of the Structure and Size Factor on the Catalytic Properties of Cobalt–Zirconium Oxide Nanoparticles in Deep Oxidation of Methane

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

We have used X-ray phase analysis, transmission electron microscopy, and temperature-programmed reduction to study cobalt–zirconium catalysts. The most active samples are characterized by higher dispersity of both the support (L = 12-13 nm) and the active component (L ≤ 3 nm); modification of the zirconium dioxide with yttrium oxide increases the thermal stability of the catalysts. We have shown that the activity of the catalysts is determined by both the strength of oxygen–catalyst binding and the acidic properties of the catalyst surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. M. Campanati, G. Fornasari, and A. Vaccari, Catal. Today, 77, 299-314 (2003).

    Google Scholar 

  2. S. N. Orlik, M. R. Kantserova, K. S. Gavrilenko, and G. R. Kosmambetova, Nanosist., Nanomater., Nanotekhnol., 1, No. 2, 529-550 (2003).

    Google Scholar 

  3. Y. Li and J. N. Armor, Appl. Catal. B., 3, No. 4, 275-282 (1994).

    Google Scholar 

  4. A. N. Kharlanov, E. V. Lunina, and V. V. Lunin, Zh. Fiz. Khim., 73, No. 5, 898-904 (1999).

    Google Scholar 

  5. V. G. Milt, M. A. Ulla, and E. A. Lombardo, Catal. Lett., 65, Nos. 1-3, 67-73 (2000).

    Google Scholar 

  6. V. R. Choudhary, S. Banerjee, and B. S. Uphade, Appl. Catal. A., 197, No. 2, L183-186 (2000).

    Google Scholar 

  7. Yu. M. Rodionov, E. M. Slyusarenko, and V. V. Lunin, Usp. Khim., 65, No. 9, 865-880 (1996).

    Google Scholar 

  8. A. S. Ivanova, Zh. Prikl. Khim., 69, No. 11, 1790-1800 (1996).

    Google Scholar 

  9. M. Labaki, J.-F. Lamonier, S. Siffert, et al., Abstracts, Sixth Russian Conference on Mechanisms of Catalytic Reactions, Moscow, 2002 [in Russian], Inst. Katal. SO RAN, Novosibirsk (2002), pp. 51-52.

    Google Scholar 

  10. V. A. Dzis'ko, A. P. Karnaukhov, and D. V. Tarasova, Physicochemical Principles for Synthesis of Oxide Catalysts [in Russian], Nauka, Novosibirsk (1978).

    Google Scholar 

  11. N. F. Uvarov and V. V. Boldyrev, Usp. Khim., 70, No. 4, 307-329 (2001).

    Google Scholar 

  12. R. Burch, D. J. Crittle, and M. J. Hayes, Catal. Today, 47, Nos. 1-4, 229-234 (1999).

    Google Scholar 

  13. V. R. Choudhary and V. H. Rane, J. Catal., 130, No. 2, 411-417 (1991).

    Google Scholar 

  14. Hsiao-Chung Wu, Liang-Chi Liu, and Sze-Ming Yang, Appl. Catal. A., 211, No. 2, 159-165 (2001).

    Google Scholar 

  15. J. Yan, M. C. Kung, W. M. H. Sachtler, et al., J. Catal., 175, No. 2, 294-303 (1998).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03028, Kyiv, Ukraine

    M. R. Kantserova & S. N. Orlik

  2. Taras Shevchenko Kyiv National University, 64 Volodymyrs@apos;ka Vul., 01033, Kyiv, Ukraine

    V. P. Kazimirov

Authors
  1. M. R. Kantserova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. N. Orlik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Kazimirov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kantserova, M.R., Orlik, S.N. & Kazimirov, V.P. Effect of the Structure and Size Factor on the Catalytic Properties of Cobalt–Zirconium Oxide Nanoparticles in Deep Oxidation of Methane. Theoretical and Experimental Chemistry 40, 246–253 (2004). https://doi.org/10.1023/B:THEC.0000041810.48201.4f

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:THEC.0000041810.48201.4f

Search

Navigation