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Interaction of Methane and Oxygen with the Surface of Manganese Oxide-Containing Catalysts

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Abstract

We used pulsed reduction and temperature programmed oxidation to study the interaction of methane and oxygen with the surface of manganese oxide-containing catalysts. We hypothesized that during oxidative dimerization of methane, the phase supplying strongly bound oxygen for selective methane coupling is an acceptor for weakly bound oxygen of the phase catalyzing exhaustive oxidation.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, 3 Akademicheskii Prospekt, 634021, Tomsk, Russia

    E. V. Bezrukov

  2. Tomsk State University, 36 Lenina Prospekt, 634050, Tomsk, Russia

    L. N. Kurina

Authors
  1. E. V. Bezrukov
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  2. L. N. Kurina
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Bezrukov, E.V., Kurina, L.N. Interaction of Methane and Oxygen with the Surface of Manganese Oxide-Containing Catalysts. Theoretical and Experimental Chemistry 40, 120–124 (2004). https://doi.org/10.1023/B:THEC.0000028908.15524.19

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  • DOI: https://doi.org/10.1023/B:THEC.0000028908.15524.19

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