Abstract
Trichlorosilane disproportionation followed by dichlorosilane separation from the resulting mixture of silicon compounds in a regularly packed distillation column is considered. The dynamic and mass-transfer properties of the regular packing are studied theoretically and experimentally. Kinetic data are calculated for distillation in a column with a bottom reboiler operated in the discrete dichlorosilane drawoff mode. The calculated data are in satisfactory agreement with experimental data.
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Vorotyntsev, V.M., Mochalov, G.M. & Kolotilova, M.A. Kinetics of Dichlorosilane Separation from a Mixture of Chlorosilanes by Distillation Using a Regular Packing. Theoretical Foundations of Chemical Engineering 38, 355–359 (2004). https://doi.org/10.1023/B:TFCE.0000037184.77958.7c
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DOI: https://doi.org/10.1023/B:TFCE.0000037184.77958.7c