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Kinetics of Ozone Formation in the Gas and Liquid Phases in a Barrier-Discharge Plasma

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Abstract

A study is undertaken to explore the kinetics of the ozone formation in the gas and liquid phases in the plasma of a barrier discharge excited in the gas (oxygen)–liquid system. It is shown that, at certain parameters of the plasma, the ozone concentrations in the gas and liquid phases become comparable. A model of a plasma chemical reactor is developed, which gives an outline of ozone synthesis. The effective rate constants for ozone decomposition in the gas and liquid phases are calculated (0.062 and 2.13 s–1, respectively).

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REFERENCES

  1. Pikaev, A.K., High Energy Chemistry at World Environmental Congress, Khim. Vys. Energ.1996}, vol. 30, no. 2, p. 155.

  2. Piskarev, I.M., Phenol Oxidation by OH*, H, O, and O3 Species Formed in Electric Discharge, Kinet. Katal., 1999, vol. 40, no. 4, p. 505.

    Google Scholar 

  3. Shvedchikov, A.P., Belousova, E.V., Polyakova, A.V., et?al., Removal of Organic Impurities from Aqueous Solutions Using a Pulsed Discharge, Khim. Vys. Energ., 1993, vol. 27, no. 1, p. 63.

    Google Scholar 

  4. Piskarev, I.M., A Model of Reactions in a Corona Discharge in the O2(g)–H2O System, Zh. Fiz. Khim., 2000, vol. 74, no. 3, p. 546.

    Google Scholar 

  5. Lunin, V.V., Popovich, M.P., and Tkachenko, S.N., Fizicheskaya khimiya ozona(Physical Chemistry of Ozone)}, Moscow: Mosk. Gos. Univ., 1998.

    Google Scholar 

  6. Bubnov, A.G., Grinevich, V.I., Kuvykin, N.A., and Maslova, O.N., Study of Surface Sewage Treatment Using a Low-Temperature Barrier-Discharge Plasma, Inzh. Ekol., 2002, no. 4, p. 27.

  7. Sabadil, H., Bachmann, P., and Kastelewicz, H., Reactionskinetik der Ozonbildung in der Sauerstoffglimmentladung, Beitr. Plasmaphys., 1980, vol. 20, no. 4, p.?283.

    Google Scholar 

  8. Bugaenko, V.L. and Byakov, V.M., Quantitative Model for the Radiolysis of Liquid Water and Dilute Aqueous Solutions of Hydrogen, Oxygen, and Hydrogen Peroxide: I. Statement of the Model, Khim. Vys. Energ., 1998, vol. 32, no. 6, p. 407.

    Google Scholar 

  9. Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz(Chemical Kinetics and Catalysis)}, Moscow: Khimiya, 1985.

    Google Scholar 

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Grinevich, V.I. Kinetics of Ozone Formation in the Gas and Liquid Phases in a Barrier-Discharge Plasma. Theoretical Foundations of Chemical Engineering 38, 56–60 (2004). https://doi.org/10.1023/B:TFCE.0000014389.49931.62

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  • DOI: https://doi.org/10.1023/B:TFCE.0000014389.49931.62

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