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Properties of Diagrams of Equilibrium Open Evaporation Accompanied by Instantaneous Chemical Reactions

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Abstract

The rules of embedding various chemical equilibrium manifolds into a concentration simplex are established. An approach to the synthesis of equilibrium distillation diagrams for the instantaneous reaction A1 + A2 ⇄ A3 + A4 is suggested. The number of possible diagram types is determined, and diagram classification is reported.

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REFERENCES

  1. Barbosa, D. and Doherty, M.F., Design and Minimum Reflux Calculation for Single-Feed Multicomponent Reactive Distillation Columns, Chem. Eng. Sci., 1988, vol. 43, p. 1523.

    Google Scholar 

  2. Barbosa, D. and Doherty, M.F., The Influence of Equilibrium Chemical Reactions on Vapor–Liquid Phase Diagrams, Chem. Eng. Sci., 1988, vol. 43, no. 3, p. 529.

    Google Scholar 

  3. Venimadhavan, G., Buzad, G., Doherty, M.F., and Malone, M.F., Effect of Kinetics on Residue Curve Maps for Reactive Distillation, AIChE J., 1994, vol. 40, p. 1814.

    Google Scholar 

  4. Pisarenko, Yu.A., Development of Theoretical Foundations for Analysis of Steady Modes of Reactive Mass-Transfer Processes, Doctoral (Tech.) Dissertation, Moscow: Lomonosov Inst. Fine Chem. Technol., 1998.

    Google Scholar 

  5. Zharov, V.T., Processes of Open Evaporation of Multicomponent Homogeneous Solutions, Zh. Fiz. Khim., 1967, vol. 41, no. 11, p. 2865.

    Google Scholar 

  6. Zharov, V.T., Thermodynamic-Topological Study of Open Phase Processes and Nonlocal Regularities of Phase Equilibrium Diagrams for Heterogeneous Systems of Various Types, Doctoral (Tech.) Dissertation, Leningrad: Leningr. State Univ., 1969.

    Google Scholar 

  7. Serafimov, L.A. and Balashov, M.I., Reactive Distillation Processes, additional chapter in Astarita, G., Massoperedacha s khimicheskoi reaktsiei(Mass Transfer with Chemical Reaction)}, Leningrad: Khimiya, 1971.

    Google Scholar 

  8. Serafimov, L.A., Azeotropic Relationship and Classification of Multicomponent Mixtures, Zh. Fiz. Khim., 1968, vol. 42, no. 1, p. 252.

    Google Scholar 

  9. Serafimov, L.A., Azeotropic Relationship and Classification of Multicomponent Mixtures: VI. Mixtures Containing n Components, Zh. Fiz. Khim., 1969, vol. 43, no.?7, p. 1753.

    Google Scholar 

  10. Zharov, V.T., Nonlocal Regularities of Liquid–Vapor Equilibrium Diagrams of Multicomponent Mixtures, Zh. Fiz. Khim., 1969, vol. 43, no. 11, p. 2785.

    Google Scholar 

  11. Serafimov, L.A., Blagov, S.A., and Solokhin, A.V., New Forms of the Azeotropic Relationships for Two-Dimensional Concentration Complexes, Teor. Osn. Khim. Tekhnol., 2000, vol. 34, no. 2, p. 178.

    Google Scholar 

  12. Aleksandrov, P.S., Vvedenie v teoriyu grupp(Introduction to Group Theory)}, Moscow: Nauka, 1980.

    Google Scholar 

  13. Grossman, I. and Magnus, W., Groups and Their Graphs, New York: Random House, 1964. Translated under the title Gruppy i ikh grafy, Moscow: Mir, 1971.

    Google Scholar 

  14. Serafimov, L.A., Azeotropic Relationship and Classification of Multicomponent Mixtures: VII. Diagrams of Ternary Mixtures, Zh. Fiz. Khim., 1970, vol. 44, no. 4, p.?1021.

    Google Scholar 

  15. Serafimov, L.A., Theoretical Principles of Construction of Flowcharts for Distillation of Nonideal Multicomponent Mixtures, Doctoral (Tech.) Dissertation, Moscow: Lomonosov Inst. Fine Chem. Technol., 1968.

    Google Scholar 

  16. Zharov, V.T. and Serafimov, L.A., Fiziko-khimicheskie osnovy distillyatsii i rektifikatsii(Physicochemical Fundamentals of Distillation)}, Leningrad: Khimiya, 1975.

    Google Scholar 

  17. Serafimov, L.A., Azeotropic Relationship and Classification of Multicomponent Mixtures, Zh. Fiz. Khim., 1967, vol. 41, no. 11, p. 2972.

    Google Scholar 

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Shalunova, S.Y., Pisarenko, Y.A., Shuvalov, A.S. et al. Properties of Diagrams of Equilibrium Open Evaporation Accompanied by Instantaneous Chemical Reactions. Theoretical Foundations of Chemical Engineering 38, 31–40 (2004). https://doi.org/10.1023/B:TFCE.0000014386.69614.5d

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  • DOI: https://doi.org/10.1023/B:TFCE.0000014386.69614.5d

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