Skip to main content
SpringerLink
Log in

Determination of Reorientation Angles from Two-Dimensional Exchange Spectra of Powders in Radiospectroscopy

  • Published:
Russian Physics Journal Aims and scope

Abstract

A method for transforming a 2D exchange spectrum into an orientation representation is proposed which is based on finding the reorientation probability as a function of angles. A procedure of evaluation and analysis of two-dimensional magnetic spectra of powders is described and a method for finding the asymmetry parameter from 2D exchange spectra is proposed. The capabilities of the method are illustrated for a model 35Cl 2D nutation exchange NQR spectrum of chloral hydrate CCl3CH(OH)2 and an experimental 13C 2D exchange NMR spectrum of dimethylsulphone CH3–SO2–CH3. The asymmetry parameter of the chemical shift tensor for this compound is determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. M. Linder, A. Hoehener, and R. R. Ernst, J. Chem. Phys., 73, 4959-4970 (1980).

    Google Scholar 

  2. C. Scmidt, S. Wefing, B. Bluemich, and H. W. Spiess, Chem. Phys. Lett, 130, 84 (1986).

    Google Scholar 

  3. B. Z. Bluemich and H. W. Spiess, Angewandte Chemie, 100, 1525-1540 (1988).

    Google Scholar 

  4. K. Schmidt-Rohr and H. W. Spiess, in: Multidimensional Solid-State NMR and Polymers, Acad. Press Ltd, London, 1996, p. 478.

    Google Scholar 

  5. N. Sinyavsky, D. Nikolajev, and M. Mackowiak, Mol. Phys., 100, 971-979 (2002).

    Google Scholar 

  6. A. Hagemeyer, L. Brombacher, K. Schmidt-Rohr, and H. W. Spiess, Chem. Phys. Lett., 167, 583-587 (1990).

    Google Scholar 

  7. C. L. Lawson and R. J. Hanson, in: Solving Least Squares Problems, Prentice-Hall, 1974, p. 161.

  8. N. Sinyavsky, M. Mackowiak, and B. Z. Bluemich, Naturforsch., 57a, 53-57 (2002).

    Google Scholar 

  9. C. Heine, NMR von Rotatorischer und Translatorischer Dynamik: Dissertation, RWTH, Aachen, Germany (2001).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Baltic State Academy of the Russian Federation, Russia

    N. Ya. Sinyavsky & I. P. Korneva

Authors
  1. N. Ya. Sinyavsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. P. Korneva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sinyavsky, N.Y., Korneva, I.P. Determination of Reorientation Angles from Two-Dimensional Exchange Spectra of Powders in Radiospectroscopy. Russian Physics Journal 47, 664–668 (2004). https://doi.org/10.1023/B:RUPJ.0000047848.81564.93

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUPJ.0000047848.81564.93

Keywords

Search

Navigation