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Theoretical and Experimental Investigation of Reactions between Dialkyl Phosphites and tert-Butylphosphaethyne

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Abstract

Experimental and theoretical study of reactions between dialkyl phosphites and tert-butylphosphaethyne revealed that the preferred reaction route resulted in formation of a phosphaalkene containing a fragment C=PP(O) including simultaneously a bicoordinate and tetracoordinate phosphorus.

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Ishmaeva, E.A., Popova, E.V., Mironov, V.F. et al. Theoretical and Experimental Investigation of Reactions between Dialkyl Phosphites and tert-Butylphosphaethyne. Russian Journal of Organic Chemistry 40, 1076–1079 (2004). https://doi.org/10.1023/B:RUJO.0000045885.25212.2b

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  • DOI: https://doi.org/10.1023/B:RUJO.0000045885.25212.2b

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