Abstract
We succeeded to observe at low temperature in reactions of trifluoromethanesulfonic anhydride and trifluoromethanesulfonyl chloride with hydrazine, phenyl hydrazine, and 1,1-dimethylhydrazine a formation of the corresponding trifluoromethanesulfonic hydrazides that at heating to room temperature decomposed liberating nitrogen and affording trifluoromethanesulfinic acid. 2-Phenyl-2H-1,2,3-triazole-4-carboxylic hydrazide reacted with trifluoromethanesulfonic anhydride to furnish trifluoro-N'-(2-phenyl-2H-1,2,3-triazol-4-ylcarbonyl)methane-sulfonic hydrazide that decomposed at heating with elimination of trifluoromethanesulfinic acid and nitrogen yielding 2-phenyl-2H-1,2,3-triazole-4-carbaldehyde.
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Shainyan, B.A., Tolstikova, L.L., Meshcheryakov, V.I. et al. Trifluoromethanesulfonic Hydrazides. Russian Journal of Organic Chemistry 40, 1071–1075 (2004). https://doi.org/10.1023/B:RUJO.0000045884.87574.ec
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DOI: https://doi.org/10.1023/B:RUJO.0000045884.87574.ec