Skip to main content
SpringerLink
Log in

Synthesis of New Iron-Containing Carbon Cages by Reaction of C60 Fullerene with Ferrocene

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

Reaction of C60 fullerene with ferrocene in the presence of aluminum chloride and aluminum in an inert atmosphere gave ferrocenyl-substituted fullerene 2C60 ·1.5(C5H5)2Fe ·3H2O. The product is a thermally stable iron-containing carbon cage in which the intersphere cavity is formed by three C60 polyhedra and is closed by cyclopentadienyl ligands via formation of four carbon-carbon bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Kochkanyan, R.O., Bondarenko, A.V., Khripunov, S.V., and Zaritovskii, A.N., Russ. J. Gen. Chem., 1995, vol. 65, p. 1085.

    Google Scholar 

  2. Zubov, E., Byszewski, P., Chabanenko, V., Kowalska, E., Gladczuk, L., and Kochkanjan, R., J. Magn. Magn. Mater., 2000, vol. 222, p. 89.

    Google Scholar 

  3. Fischer, E.O. and Hafner, F., Z. Naturforsch., 1955, p. 665.

  4. Crane, J., Hitchcock, P., Kroto, H., Taylor, R., and Walton, D., J. Chem. Soc., Chem. Commun., 1992, p. 1764.

  5. Gol'dshleger, N.F. and Moravskii, A.P., Usp. Khim., 1997, vol. 66, p. 353.

    Google Scholar 

  6. Kazitsyna, L.I. and Kupletskaya, N.B., Primenenie UF-, IK-i YaMR-spektroskopii v organicheskoi khimii(Application of UV, IR, and NMR Spectroscopy in Organic Chemistry), Moscow: Vysshaya Shkola, 1971, p. 53.

    Google Scholar 

  7. Krätschmer, W., Lamb, L.D., Fostiropoulos, K., and Huffman, D.R., Nature, 1990, vol. 347, p. 354.

    Google Scholar 

  8. Pradeep, T., Kulkarni, G.U., Kannan, K.R., Guru Row, T.N., and Rao, C.N.R., J. Am. Chem. Soc., 1992, vol. 114, p. 2272.

    Google Scholar 

  9. McEwen, C.N., McKay, R.G., and Larsen, B.S., J. Am. Chem. Soc., 1992, vol. 114, p. 4412.

    Google Scholar 

  10. Makarova, T.L., Fizika i tekhnika poluprovodnikov(Physics and Technics of Semiconductors), 2001, vol. 35, p. 257.

    Google Scholar 

Download references

Authors
  1. R. O. Kochkanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Nechitailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Byszewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Zaritovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. F. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kochkanyan, R.O., Nechitailov, M.M., Byszewski, P. et al. Synthesis of New Iron-Containing Carbon Cages by Reaction of C60 Fullerene with Ferrocene. Russian Journal of Organic Chemistry 40, 957–961 (2004). https://doi.org/10.1023/B:RUJO.0000045184.26881.7c

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUJO.0000045184.26881.7c

Keywords

Search

Navigation