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Synthesis and Complexing Properties of Alkyl (3-Oxo-2,3-dihydrothiophen-2-ylidene)- and (4-Oxothiazolidin-5-ylidene)acetate Derivatives

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Abstract

Condensation of dimethyl and diethyl acetylenedicarboxylate with thioacetamides gave the corresponding alkyl (3-oxo-2,3-dihydrothiophen-2-ylidene)- and (4-oxothiazolidin-5-ylidene)acetates. Treatment of these compounds with zinc in acetic acid resulted in reduction of the exocyclic double bonds. The products can be used in membrane processes as sodium cation carriers.

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Authors and Affiliations

  1. Ural State Technical University, ul. Mira 19, Yekaterinburg, 620002, Russia

    M. F. Kosterina, Yu. Yu. Morzherin, O. A. Kramarenko, V. S. Berseneva & A. I. Matern

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

    A. V. Tkachev & V. A. Bakulev

Authors
  1. M. F. Kosterina
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  2. Yu. Yu. Morzherin
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  3. O. A. Kramarenko
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  4. V. S. Berseneva
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  5. A. I. Matern
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  6. A. V. Tkachev
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  7. V. A. Bakulev
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Kosterina, M.F., Morzherin, Y.Y., Kramarenko, O.A. et al. Synthesis and Complexing Properties of Alkyl (3-Oxo-2,3-dihydrothiophen-2-ylidene)- and (4-Oxothiazolidin-5-ylidene)acetate Derivatives. Russian Journal of Organic Chemistry 40, 866–869 (2004). https://doi.org/10.1023/B:RUJO.0000044550.62124.94

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  • DOI: https://doi.org/10.1023/B:RUJO.0000044550.62124.94

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