Abstract
1,3-Dinitrobenzene and some its 2- and 4-substituted derivatives are dehydroaminated in a solution of potassium permanganate in liquid ammonia to give the corresponding mono- or diamino-1,3-dinitro-benzenes. Under the same conditions, 4-fluoro-1,3-dinitrobenzene is converted into 2,4-dinitroaniline via replacement of the fluorine atom, while 2,4-dinitrobenzaldehyde gives rise to 2,4-dinitrobenzamide.
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Szpakiewicz, B., Grzegozek, M. Amination of Some 1,3-Dinitrobenzenes with Liquid Ammonia–Potassium Permanganate. Russian Journal of Organic Chemistry 40, 829–833 (2004). https://doi.org/10.1023/B:RUJO.0000044545.10133.96
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DOI: https://doi.org/10.1023/B:RUJO.0000044545.10133.96