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Preparative Synthesis and Structure of 2,2-Bis(hydroxymethyl)propyl and 2,2-Bis(hydroxy-methyl)butyl Phosphites

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Abstract

Conditions were found for selective hydrolysis of bicyclic phosphites derived from 2,2-bis-(hydroxymethyl)-1-propanol and 2,2-bis(hydroxymethyl)-1-butanol to the corresponding dihydrogen phosphites. The latter were isolated as potassium, sodium, and ammonium salts and were characterized by the 1H, 13C, and 31P NMR spectra. The structure of the ammonium salt was proved by X-ray analysis.

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Authors and Affiliations

  1. Moscow State Pedagogical University, Nesvizhskii per. 3, Moscow, 119021, Russia

    A. M. Koroteev, G. B. Krasnov, M. P. Koroteev & E. E. Nifant’ev

  2. Nesmeyanov Institute of Organometallic Compounds, ul. Vavilova 28, Moscow, 117813, Russia

    L. N. Kulesheva, M. Yu. Antipin & A. A. Korlyukov

Authors
  1. A. M. Koroteev
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  2. G. B. Krasnov
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  3. M. P. Koroteev
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  4. E. E. Nifant’ev
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  5. L. N. Kulesheva
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  6. M. Yu. Antipin
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  7. A. A. Korlyukov
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Koroteev, A.M., Krasnov, G.B., Koroteev, M.P. et al. Preparative Synthesis and Structure of 2,2-Bis(hydroxymethyl)propyl and 2,2-Bis(hydroxy-methyl)butyl Phosphites. Russian Journal of Organic Chemistry 40, 474–478 (2004). https://doi.org/10.1023/B:RUJO.0000036065.86568.19

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  • DOI: https://doi.org/10.1023/B:RUJO.0000036065.86568.19

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