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First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes

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Abstract

Carbonyl ylide generated from 1-diazo-5-phenylpentane-2,5-dione in the presence of Rh2(OAc)4 reacts with 3-substituted cyclopropenes following the 1,3-dipolar cycloaddition pattern to afford substituted 9-oxatricyclo[3.3.1.02,4]nonan-6-ones.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    A. P. Molchanov, V. V. Diev & R. R. Kostikov

  2. Institut für anorganische Chemie, Hamburg, Germany

    J. Kopf

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  1. A. P. Molchanov
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  2. V. V. Diev
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  3. J. Kopf
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  4. R. R. Kostikov
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Molchanov, A.P., Diev, V.V., Kopf, J. et al. First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes. Russian Journal of Organic Chemistry 40, 431–433 (2004). https://doi.org/10.1023/B:RUJO.0000034985.42542.e6

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  • DOI: https://doi.org/10.1023/B:RUJO.0000034985.42542.e6

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