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First Example of Trifluoromethylation in the Ecdysteroid Series. Synthesis of (20RS)-20-O-Hydro-20-trifluoromethylpoststerone

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Abstract

The title compound was synthesized by trifluoromethylation of poststerone derivatives with trimethyl(trifluoromethyl)silane in the presence of tetrabutylammonium fluoride.

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REFERENCES

  1. Enantiocontrolled Synthesis of Organo-Fluorine Compounds: Stereochemical Challenge and Biochemical Targets, Sholoshonok, V.A., Ed., New York: Wiley, 1999.

    Google Scholar 

  2. Singh, R.P. and Shreeve, J.M., Tetrahedron, 2000, vol. 56, p. 7613.

    Google Scholar 

  3. Olah, G.A., Prakash, G.K.S., and Chambers, R.D., Synthetic Fluorine Chemistry, New York: Wiley, 1992.

    Google Scholar 

  4. Prakash, S.G.K. and Yudin, A.K., Chem. Rev., 1997, vol. 97, p. 757.

    Google Scholar 

  5. Odinokov, V.N., Savchenko, R.G., Nazmeeva, S.R., and Galyautdinov, I.V., Izv. Ross. Akad. Nauk, Ser. Khim., 2002, p. 1784.

  6. Odinokov, V.N., Savchenko, R.G., Nazmeeva, S.R., and Galyautdinov, I.V., Izv. Ross. Akad. Nauk, Ser. Khim., 2002, p. 1810.

  7. Galbraith, M.N., Horn, D.N.S., Middleton, E.J., and Hackney, R.J., Aust. J. Chem., 1969, vol. 22, p. 1517.

    Google Scholar 

  8. Odinokov, V.N., Galyautdinov, I.V., Nedopekin, D.V., Khalilov, L.M., Shashkov, A.S., Kachala, V.V., Dinan, L., and Lafont, R., Insect Biochem. Mol. Biol., 2002, vol. 32, p. 161.

    Google Scholar 

  9. Lafont, R.D. and Wilson, I.D., The Ecdysone Handbook, Nottingham: Chromatographic Society, 2000, 3rd ed.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Academy of Sciences of Bashkortostan and Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075 Bashkortostan, Russia

    V. N. Odinokov, S. R. Nazmeeva & R. G. Savchenko

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  1. V. N. Odinokov
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  2. S. R. Nazmeeva
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  3. R. G. Savchenko
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Odinokov, V.N., Nazmeeva, S.R. & Savchenko, R.G. First Example of Trifluoromethylation in the Ecdysteroid Series. Synthesis of (20RS)-20-O-Hydro-20-trifluoromethylpoststerone. Russian Journal of Organic Chemistry 39, 1733–1737 (2003). https://doi.org/10.1023/B:RUJO.0000019736.80902.6e

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  • DOI: https://doi.org/10.1023/B:RUJO.0000019736.80902.6e

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