Skip to main content
SpringerLink
Log in

Structure of Potassium Carbonate Complexes with Phenols and Thiophenols in Aproyic Dipolar Solvents

  • Published:
Russian Journal of Organic Chemistry Aims and scope Submit manuscript

Abstract

By means of IR, 1H, 13C, and 39K NMR spectroscopy the potassium carbonate was demonstrated to form complexes with phenols and thiophenols in aprotic dipolar solvents of the composition (2ArXH)-K2CO3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Sasson, Y. and Bilman, N., J. Chem. Soc., Perkin Trans. II, 1989, p. 2029.

  2. Landini, D. and Penso, M., J. Org. Chem., 1991, vol. 56, p. 421; Albanese, D., Landini, D., Maia, A., and Penso,M., J. Mol. Cat. A: Chem., 1990, vol. 150, p. 113.

    Google Scholar 

  3. Shevelev, S.A., Dutov, M.D., Vatsadze, I.A., Serushkina, O.V., Rusanov, A.L., and Andrievskii, A.M., Mendeleev Commun., 1995, p. 157; Shevelev, S.A., Dutov, M.D., and Serushkina, O.V., Izv. Akad, Nauk, Ser. Khim., 1995, p. 2528; Shimata, K., Yoshisato, A., and Yoshitomi, T., Japan Patent 07118212, 1995; Chem. Abstr., 1995, vol. 123, p. 82943; Yamaguchi, K., Yoshihawa, Y., Tamai, S., Sugitomo, K., Tanabe, Y., Yamaguchi, A., Europe Patent 193358, 1986; Chem. Abstr., 1986, vol. 105, p. 226036q; Williams, F.J., Relles, H. M., Manello, J.S., and Donahue, P.E., J. Org. Chem., 1977, vol. 42, p. 3419.

  4. Kaninskii, P.S., Plakhtinskii, V.V., Mironov, G.S., and Ryabukhina, N.S., Osn. Org. Sintez i Neftekhimiya, 1986, p. 76; Dorogov, M.V., Yasinskii, O.A., Plakhtinskii, V.V., and Pliss, E.M., Zh. Org. Khim., 1999, vol. 35, p. 1199.

  5. Khalfina, I.A. and Vlasov, V.M., Zh. Org. Khim., 2001, vol. 38, p. 56.

    Google Scholar 

  6. Vlasov, V.M. and Khalfina, I.A., J. Phys. Org. Chem., 2000, p. 630.

  7. Bordwell, F.G. and Cheng, J.-P., J. Am. Chem. Soc., 1991, vol. 113, p. 1736.

    Google Scholar 

  8. Williams, F.J. and Donahue, P.E., J. Org. Chem., 1978, vol. 43, p. 250.

    Google Scholar 

  9. Emsley, J.W., Feeney, J., and Sutcliffe, L.H., High-Resolution Nuclear Magnetic Resonance Spectroscopy, Oxford: Pergamon, 1966, vol. 2. Translated under the title Spektroskopiya YaMR vysokogo razresheniya, Moscow: Mir, 1969, vol. 1, p. 32.

    Google Scholar 

  10. Tinkhman, M.L. and Dye, J. L., J. Am. Chem. Soc., 1985, vol. 107, p. 6129.

    Google Scholar 

  11. Nakamoto, K., Infra-Red Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1963.

    Google Scholar 

  12. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959; Translated under the title Spektry yadernogo magnitnogo rezonansa vysokogo razresheniya, Moscow: Inostr. Lit., 1962, p. 531.

    Google Scholar 

  13. Brand, J.C.D. and Eglinton, G., Applications of Spectroscopy to Organic Chemistry, London: Oldbourne, 1965.

    Google Scholar 

  14. Bellamy, L.J., The Infra-red Spectra of Complex Molecules, London: Methuen, 1958. Translated under the title Infrakrasnye spektry slozhnykh molekul, Moscow: Inostr. Lit., 1963, p. 552.

    Google Scholar 

  15. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959; Translated under the title Spektry yadernogo magnitnogo rezonansa vysokogo razresheniya, Moscow: Inostr. Lit., 1962, p. 218.

    Google Scholar 

  16. Bellamy, L.J., The Infra-red Spectra of Complex Molecules, London: Methuen, 1958. Translated under the title Infrakrasnye spektry slozhnykh molekul, Moscow: Inostr. Lit., 1963, p. 178.

    Google Scholar 

  17. Levy, G.C. and Nelson, G.L., Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, New York: Wiley, 1972. Translated under the title Rukovodstvo po yadernomu magnitnomu rezonansu ugleroda-13 dlya khimikov-organikov, Moscow: Mir, 1975, p. 46.

    Google Scholar 

  18. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959; Translated under the title Spektry yadernogo magnitnogo rezonansa vysokogo razresheniya, Moscow: Inostr. Lit., 1962, p. 477.

    Google Scholar 

  19. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959; Translated under the title Spektry yadernogo magnitnogo rezonansa vysokogo razresheniya, Moscow: Inostr. Lit., 1962, p. 119.

    Google Scholar 

  20. Micellization, Solubilization, and Microemulsions, Mittall, K., Ed., New York: Plenum, 1977.

  21. Molecular Interactions, Ratajczak, H. and Orville-Thomas, W.J., Eds., Chichester: Wiley, 1981, vol. 2.

  22. Pople, J.A., Schneider, W.G., and Bernstein, H.J., High-Resolution Nuclear Magnetic Resonance, New York: McGraw-Hill, 1959; Translated under the title Spektry yadernogo magnitnogo rezonansa vysokogo razresheniya, Moscow: Inostr. Lit., 1962, p. 42.

    Google Scholar 

  23. Kaninskii, P.S., Abramov, I.G., Yasinskii, O.A., Mironov, G.S., and Plakhtinskii, V.V., Zh. Org. Khim., 1992, vol. 28, p. 1232.

    Google Scholar 

  24. Levy, G.C. and Nelson, G.L., Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, New York: Wiley, 1972. Translated under the title Rukovodstvo po yadernomu magnitnomu rezonansu ugleroda-13 dlya khimikov-organikov, Moscow: Mir, 1975, p. 146.

    Google Scholar 

  25. Chemical Reactivity and Reaction Paths, Klopman, G., Ed., New York: Wiley, 1974.

  26. Kornblum, N. and Lurie, A.P., J. Am. Chem. Soc., 1959, vol. 81, p. 2705.

    Google Scholar 

  27. Stewart, J.J.P., QCPE, no. 455.

Download references

Author information

Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    I. A. Khalfina, I. V. Beregovaya & V. M. Vlasov

Authors
  1. I. A. Khalfina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. V. Beregovaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Vlasov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khalfina, I.A., Beregovaya, I.V. & Vlasov, V.M. Structure of Potassium Carbonate Complexes with Phenols and Thiophenols in Aproyic Dipolar Solvents. Russian Journal of Organic Chemistry 39, 1104–1115 (2003). https://doi.org/10.1023/B:RUJO.0000010177.50684.3b

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUJO.0000010177.50684.3b

Keywords

Search

Navigation