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Reaction of Perfluoro-1-methylbenzocyclobutene with Pentafluorobenzene in SbF5 Medium

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Abstract

A reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium followed by treating the reaction mixture with water gave rise to perfluoro-1-methyl-1-phenylbenzocyclobutene, perfluoro-1-methyl-2-phenylbenzocyclobutene, 2-hydroxyperfluoro-1-methyl-2-phenylbenzocyclobutene, and also to small amounts of 1-(2-trifluoromethyltetrafluorophenyl)-1-pentafluorophenyl-2,2,2-trifluoroethane, and perfluoro-1-(2-methylphenyl)-1-phenylethylene. In a crystal of (E)-2-hydroxyperfluoro-1-methyl-2-phenylbenzocyclobutene for a dimer molecular pair a π-stacking interaction between pentafluorophenyl groups was found.

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Authors and Affiliations

  1. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. R. Sinyakov, T. V. Mezhenkova, V. M. Karpov, V. E. Platonov, T. V. Rybalova & Yu. V. Gatilov

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  1. V. R. Sinyakov
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  2. T. V. Mezhenkova
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  3. V. M. Karpov
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  4. V. E. Platonov
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  5. T. V. Rybalova
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  6. Yu. V. Gatilov
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Sinyakov, V.R., Mezhenkova, T.V., Karpov, V.M. et al. Reaction of Perfluoro-1-methylbenzocyclobutene with Pentafluorobenzene in SbF5 Medium. Russian Journal of Organic Chemistry 39, 837–842 (2003). https://doi.org/10.1023/B:RUJO.0000003162.41792.ad

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  • DOI: https://doi.org/10.1023/B:RUJO.0000003162.41792.ad

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