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Stevens Rearrangement of Ammonium Salts Containing 3-Methyl-3-ethoxycarbonylbutanon-2-yl Group

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Abstract

Ammonium salts containing alongside 3-methyl-3-ethoxycarbonylbutanon-2-yl also 2-alkenyl or benzyl groups under the treatment with Na2CO3·10H2O afford products resulting from Stevens rearrangement. In the mentioned salts the ketoester group on treatment with sodium ethylate suspension in ether or benzene suffers partial or total acid cleavage, and then the Stevens 3,2-rearrangement takes place.

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Authors and Affiliations

  1. Abovyan Armenien State Pedagogical University, Armenia

    A. V. Babakhanyan

  2. Institute of Organic Chemistry, National Academy of Sciences of Armenia, Yerevan, 375091, Armenia

    V. S. Ovsepyan & S. T. Kocharyan

  3. Center for Investigation of Molecular Structure, Yerevan, Armenia

    G. A. Panosyan

Authors
  1. A. V. Babakhanyan
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  2. V. S. Ovsepyan
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  3. S. T. Kocharyan
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  4. G. A. Panosyan
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Babakhanyan, A.V., Ovsepyan, V.S., Kocharyan, S.T. et al. Stevens Rearrangement of Ammonium Salts Containing 3-Methyl-3-ethoxycarbonylbutanon-2-yl Group. Russian Journal of Organic Chemistry 39, 820–824 (2003). https://doi.org/10.1023/B:RUJO.0000003158.77574.20

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  • DOI: https://doi.org/10.1023/B:RUJO.0000003158.77574.20

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