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Hydrophosphorylation of Terminal Alkynes Catalyzed by Palladium

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Abstract

A series of new 1-aryl-, 1-heteroaryl-, and 1-alkylethenylphosphonates was prepared by hydrophosphorylation of terminal acetylenes catalyzed by palladium. A stable in air complex Pd2(dba)3·CHCl3 was applied as catalyst. The reaction mechanism is discussed.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119899, Russia

    N. S. Gulykina, T. M. Dolgina, G. N. Bondarenko & I. P. Beletskaya

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  1. N. S. Gulykina
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  2. T. M. Dolgina
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  3. G. N. Bondarenko
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  4. I. P. Beletskaya
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Gulykina, N.S., Dolgina, T.M., Bondarenko, G.N. et al. Hydrophosphorylation of Terminal Alkynes Catalyzed by Palladium. Russian Journal of Organic Chemistry 39, 797–807 (2003). https://doi.org/10.1023/B:RUJO.0000003155.15312.f4

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