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Kinetics of Mercuration of 2- and 4-Methyl-containing Salts of Heterocyclic Cations

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Abstract

Kinetics of the monomercuration by the active methyl groups of 2- and 4-methyl-containing salts of quinolinium, pyridinium, benzothiazolium, and pyrrilium with mercury(II) acetate and trifluoroacetate in a mixture of anhydrous ethanol and acetonitrile (3:1) at 50-70°C were studied by means of acid-base potentiometric titration. The apparent second-order rate constants of these reactions were estimated, and factors affecting their rate were considered. A mechanism of the reactions was offered.

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Authors and Affiliations

  1. Lipetsk State Pedagogical University, Lipetsk, Russia

    S. V. Yadrovskii, A. I. Moskalenko & V. I. Boev

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  1. S. V. Yadrovskii
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  2. A. I. Moskalenko
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  3. V. I. Boev
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Yadrovskii, S.V., Moskalenko, A.I. & Boev, V.I. Kinetics of Mercuration of 2- and 4-Methyl-containing Salts of Heterocyclic Cations. Russian Journal of General Chemistry 74, 767–771 (2004). https://doi.org/10.1023/B:RUGC.0000039092.32109.13

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  • DOI: https://doi.org/10.1023/B:RUGC.0000039092.32109.13

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