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Reaction of the System Arene(Hetarene)thiol-Diselenide with Phenylacetylene

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Abstract

Liquid-phase thermal reactions of phenylacetylene with the system arene(hetarene)thioldiselenide at 110-180°C proceed through conjugate addition to the phenylacetylene triple bond of one alkylselanyl and one arene(hetarenesulfanyl groups to form 2-alkylselanyl-2-[aryl(hetaryl)sulfanyl]-1-phenylethenes and 1-alkylselanyl-2-[aryl(hetaryl)sulfanyl]-1-phenylethenes. Therewith, direct addition of thiols to phenylacetylene slows down.

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REFERENCES

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    L. K. Papernaya, A. I. Albanov, E. N. Sukhomazova, E. P. Levanova & E. N. Deryagina

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  1. L. K. Papernaya
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  2. A. I. Albanov
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  3. E. N. Sukhomazova
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  4. E. P. Levanova
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  5. E. N. Deryagina
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Papernaya, L.K., Albanov, A.I., Sukhomazova, E.N. et al. Reaction of the System Arene(Hetarene)thiol-Diselenide with Phenylacetylene. Russian Journal of General Chemistry 74, 708–712 (2004). https://doi.org/10.1023/B:RUGC.0000039083.59169.f3

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  • DOI: https://doi.org/10.1023/B:RUGC.0000039083.59169.f3

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