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Cation Distribution and Interatomic Interactions in Oxides with Heterovalent Isomorphism: VIII.1 A High-Temperature Study of the Structure of Gd2SrAl2O3

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Abstract

The interatomic distances and distribution of gadolinium and strontium cations over two positions in the structure of Gd2SrAl2O3 at 1273 K were determined by full-profile X-ray diffraction analysis. A comparative analysis was made of the anisotropy of thermal expansion of the coordination polyhedra in layered perovskite-like structures of the Sr3Ti2O7 and K2NiF4 types.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    I. A. Zvereva, Yu. E. Smirnov & J. Choisnet

  2. University of Caen, Caen, France

    I. A. Zvereva, Yu. E. Smirnov & J. Choisnet

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  1. I. A. Zvereva
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  2. Yu. E. Smirnov
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  3. J. Choisnet
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Zvereva, I.A., Smirnov, Y.E. & Choisnet, J. Cation Distribution and Interatomic Interactions in Oxides with Heterovalent Isomorphism: VIII.1 A High-Temperature Study of the Structure of Gd2SrAl2O3 . Russian Journal of General Chemistry 74, 655–658 (2004). https://doi.org/10.1023/B:RUGC.0000039072.46257.b6

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  • DOI: https://doi.org/10.1023/B:RUGC.0000039072.46257.b6

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