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Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex

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Abstract

The catalytic oxidation of iron(II) with oxygen occurs along with an autocatalytic reaction between palladium(II) tetraaqua complex and iron(II) aqua complex in an oxygen atmosphere. The reaction is catalyzed by a compound of palladium in an intermediate oxidation state, presumably by a small palladium cluster formed in the course of the reduction of palladium(II) tetraaqua complex with iron(II) aqua complex.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, St. Petersburg, Russia

    V. V. Potekhin, S. N. Solov'eva & V. M. Potekhin

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  1. V. V. Potekhin
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  2. S. N. Solov'eva
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  3. V. M. Potekhin
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Potekhin, V.V., Solov'eva, S.N. & Potekhin, V.M. Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex. Russian Journal of General Chemistry 74, 647–650 (2004). https://doi.org/10.1023/B:RUGC.0000039070.98591.c1

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  • DOI: https://doi.org/10.1023/B:RUGC.0000039070.98591.c1

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