Abstract
Substituted amides and esters of 3,4,4-trichloro-3-butenoic acid were prepared by reactions of its chloride with appropriate amines and alcohols. Treatment of 3,4,4-trichloro-3-butenomorpholide and tert-butyl 3,4,4-trichloro-3-butenoate results in nucleophilic substitution of the internal chlorine atom with the morpholine residue, accompanied by prototropic allyl rearrangement.
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Petkevich, S.K., Dikusar, E.A., Potkin, V.I. et al. Functionally Substituted Amides and Esters of 3,4,4-Trichloro-3-butenoic Acid. Russian Journal of General Chemistry 74, 586–593 (2004). https://doi.org/10.1023/B:RUGC.0000031862.88263.de
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DOI: https://doi.org/10.1023/B:RUGC.0000031862.88263.de