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Hydrosilylation of Aromatic Azomethines

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Abstract

The reactions of aromatic azomethines with methyldichlorosilane, phenyldichlorosilane, and dimethylchlorosilane, performed in the presence of Speier's, Wilkinson's, and Karstedt's catalysts and a series of Pt(II) complexes LL'PtCl2, give hydrosilylation and reduction products whose ratio depends on the catalyst used. The highest yield of hydrosilylation products is attained with Pt(II) complexes as catalysts.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    V. V. Zuev, O. P. Kovaleva & N. K. Skvortsov

  2. St. Petersburg State Institute of Technology, St. Petersburg, Russia

    V. V. Zuev, O. P. Kovaleva & N. K. Skvortsov

Authors
  1. V. V. Zuev
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  2. O. P. Kovaleva
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  3. N. K. Skvortsov
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Zuev, V.V., Kovaleva, O.P. & Skvortsov, N.K. Hydrosilylation of Aromatic Azomethines. Russian Journal of General Chemistry 74, 548–550 (2004). https://doi.org/10.1023/B:RUGC.0000031855.77108.f6

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  • DOI: https://doi.org/10.1023/B:RUGC.0000031855.77108.f6

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