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Synthesis on Silica Surface by the Ionic Deposition Technique of Nanolayers of Heteropolycompounds on the Basis of Phosphomolybdic Acid

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Abstract

Layers of a “hybrid” iso- and heteropolycompound of the composition Zr2.6(OH) x PMo8.0Sn1.9O y · nH2O were obtained on silica surface by ionic deposition. Heating in air at 200-400°C results in removal from the layer of water molecules, oxidation of Mo5+ to Mo6+, and formation of Mo-O-Zr and Mo-O-Sn chemical bonds.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    L. B. Gulina & V. P. Tolstoi

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  1. L. B. Gulina
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  2. V. P. Tolstoi
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Gulina, L.B., Tolstoi, V.P. Synthesis on Silica Surface by the Ionic Deposition Technique of Nanolayers of Heteropolycompounds on the Basis of Phosphomolybdic Acid. Russian Journal of General Chemistry 74, 327–330 (2004). https://doi.org/10.1023/B:RUGC.0000030385.08390.77

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  • DOI: https://doi.org/10.1023/B:RUGC.0000030385.08390.77

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