Abstract
Unlike isoelectronic η6-indenyl ruthenium, manganese, and chromium complexes, heating of Mn(CO)5OTf, [Ru(Cp*)Cl4], and Cr(C10H8)(CO)3 with isomeric 2-ethyl-5-methylcyclopenta[b]thiophenes leads to the corresponding η5-complexes where the metal is coordinated at the C5-carbocycle. The structure of the complex Mn(Th)(CO)3 (Th = 2-ethyl-5-methylcyclopenta[b]thienyl) was proved by X-ray analysis.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Kisun'ko, D.A., Zabalov, M.V., Oprunenko, Yu.F., Myshakin, E.M., and Lemenovskii, D.A., Izv. Ross. Akad. Nauk, Ser. Khim., 2000, no. 17, p. 2346.
Kissounko, D.A., Oprunenko, Yu.F., Lemenovski, D.A., and Boag, N.M., Book of Abstracts, XIIIth FECHEM Organometallic Conf., Lisbon, 1999, p. 28.
Kissounko, D.A., Oprunenko, Yu.F., Lemenovskii, D.A., and Boag, N.M., Book of Abstracts, XIIIth FECHEM Organometallic Conf., Lisbon, 1999, p. 145.
Lemenovskii, D.A., Kissounko, D.A., Zabalov, M.V., Oprunenko, Yu.F., and Boag, N.M., Abstracts of Papers, XIIIth Int. Organometallic Conf., Shanghai, 2000, p. 104.
Ustynyuk, N.A., Lokshin, B.V., Oprunenko, Yu.F., Roznyatovsky, V.A., Luzikov, Yu.N., and Ustynyuk, Yu.A., J. Organomet. Chem., 1980, vol. 202, p. 279.
Nesmeyanov, A.N., Ustynyuk, N.A., Novikova, L.N., Rybina, T.N., Ustynyuk, Yu.A., Oprunenko, Yu.F., and Trifonova, O.I., J. Organomet. Chem., 1980, vol. 184, p. 63.
Triechel, P.M. and Jonson, J.E., J. Organomet. Chem., 1975, vol. 88, p. 207.
Kudinov, A.R., Petrovskii, P.V., Struchkov, Yu.T., Yanovskii, A.I., and Rybinskaya, M.I., J. Organomet. Chem., 1991, vol. 421, p. 91.
Nesmeyanov, A.N., Ustynyuk, N.A., Makarova, L.G., Andrianov, V.G., Andrae, S., Novikova, L.N., Ustynyuk, Yu.A., and Luzikov, Yu.N., J. Organomet. Chem., 1978, vol. 154, p. 45.
Jimenez-Tenorio, M., Puerta, M.M., and Valegra, P., Organometallics, 1994, vol. 13,no. 4, p. 1330.
Loft, M.S., Mowlem, T.J., and Widdowson, D.A., J. Chem. Soc., Perkin Trans. 1, 1995, no. 2, p. 97.
Loft, M.S., Mowlem, T.J., Widdowson, D.A., and Williams, D.J., J. Chem. Soc., Perkin Trans. 1, 1995, no. 2, p. 105.
Huckett, S.C., Sauer, N.N., and Angelici, R.J., Organometallics, 1987, vol. 6,no. 3, p. 591.
Huckett, S.C., Miller, L.L., Jacobson, R.A., and Angelici, R.J., Organometallics, 1998, vol. 17,no. 4, p. 686.
Luo, S., Rauchfuss, T.B., and Wilson, S.R., J. Am. Chem. Soc., 1992, vol. 114,no. 22, p. 8513.
Rauchfuss, T.B., Prog. Inorg. Chem., 1991, vol. 31, p. 259.
Bell, W.L., Curtis, C.L., Eigenbrot, C.W., Pierpont, J.C.G., Robbins, J.L., and Smart, J.C., Organometallics, 1987, vol. 6,no. 2, p. 270.
Wasserman, H.J., Kubas, G.J., and Ryan, R.R., J. Am. Chem. Soc., 1986, vol. 108,no. 9, p. 2294.
Voltz, H. and Kowarsch, H., Tetrahedron Lett., 1976, no. 48, p. 4376.
Lesh, D.A., Richardson, J.W., Jacobson, R.A., and Angelici, R.J., J. Am. Chem. Soc., 1984, vol. 106,no. 10, p. 2901.
Desorby, V. and Kundig, E.P., Helv. Chim. Acta, 1981, vol. 64,no. 5, p. 1288.
Koelle, U. and Kosakowskii, J., Inorganic Syntheses, Grimer, R.S., New York: Wiley, 1992, vol. 29, p. 226.
Sheldrick, G.M., SHELXS97, Göttingen: Univ. of Gottingen, 1997.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kisun'ko, D.A., Zabalov, M.V., Oprunenko, Y.F. et al. Cyclopenta[b]thienyl Ligand in Organometallic Chemistry. Synthesis of Cyclopenta[b]thiophene η5-Complexes with Metal Coordination at the Thiophene Ring. Russian Journal of General Chemistry 74, 105–109 (2004). https://doi.org/10.1023/B:RUGC.0000025177.78155.a1
Issue Date:
DOI: https://doi.org/10.1023/B:RUGC.0000025177.78155.a1