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Reactions of 2-Alkoxy-4-oxo-5,6-benzo- 1,3,2-dioxaphosphorinanes with Imines. Synthesis and Steric Structure of 6,7-Benzo-1,4,2-oxazaphosphepine Derivatives

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Abstract

2-Alkoxy-4-oxo-5,6-benzo-1,3,2-dioxaphosphorinanes containing an electron-withdrawing fluorinated exocyclic substituent at the P atom react with aromatic aldimines to give 6,7-benzo-1,4,2-oxaza- phosphepines with a high regio- and stereoselectivity. The major diastereomers were isolated, and their configuration was determined by single crystal X-ray diffraction.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    V. F. Mironov, A. T. Gubaidullin, L. M. Burnaeva, I. A. Litvinov, G. A. Ivkova, S. V. Romanov, T. A. Zyablikova, A. I. Konovalov & I. V. Konovalova

  2. Kazan State University, Kazan, Tatarstan, Russia

    V. F. Mironov

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  1. V. F. Mironov
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  2. A. T. Gubaidullin
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Mironov, V.F., Gubaidullin, A.T., Burnaeva, L.M. et al. Reactions of 2-Alkoxy-4-oxo-5,6-benzo- 1,3,2-dioxaphosphorinanes with Imines. Synthesis and Steric Structure of 6,7-Benzo-1,4,2-oxazaphosphepine Derivatives. Russian Journal of General Chemistry 74, 32–47 (2004). https://doi.org/10.1023/B:RUGC.0000025168.52989.62

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