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Electrophilic Copper(II) → Metal(II) Substitution in Gelatin-Immobilized Copper(II) Hexacyanoferrate(II) Matrix Implants

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Abstract

Contact of thin layers of gelatin-immobilized copper(II) hexacyanoferrate(II) matrices with aqueous solutions of Co(II), Ni(II), Zn(II), and Cd(II) chlorides results in partial substitution of these ions for Cu(II) to give (dd)-heterobinuclear hexacyanoferrates(II) of copper(II) and the corresponding double-charged ion.

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Authors and Affiliations

  1. Kazan State Technological University, Kazan, Tatarstan, Russia

    O. V. Mikhailov, T. B. Tatarintseva, N. I. Naumkina & T. Z. Lygina

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  1. O. V. Mikhailov
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  2. T. B. Tatarintseva
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  3. N. I. Naumkina
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  4. T. Z. Lygina
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Mikhailov, O.V., Tatarintseva, T.B., Naumkina, N.I. et al. Electrophilic Copper(II) → Metal(II) Substitution in Gelatin-Immobilized Copper(II) Hexacyanoferrate(II) Matrix Implants. Russian Journal of General Chemistry 74, 7–12 (2004). https://doi.org/10.1023/B:RUGC.0000025165.97632.63

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  • DOI: https://doi.org/10.1023/B:RUGC.0000025165.97632.63

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