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Synthesis and Complex-Forming Properties of N-Substituted Diazacrown Ethers

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Abstract

N-Substituted mono- and diazacrown ether with ethoxycarbonylmethyl, 7-phenyl-3,6-dioxaheptyl, p-methoxy, and p-nitrobenzyl groups in the side chain have been synthesized. Their reactions with alkali and alkaline-earth metals have been studied. Substituents affect the complex-forming ability of the “base” macrocycle by changing the basicity of the nitrogen atoms and coordinating with the complexing ion.

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Authors and Affiliations

  1. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine

    N. G. Luk'yanenko, S. S. Basok, E. Yu. Kulygina & V. I. Vetrogon

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  1. N. G. Luk'yanenko
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  2. S. S. Basok
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  3. E. Yu. Kulygina
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  4. V. I. Vetrogon
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Luk'yanenko, N.G., Basok, S.S., Kulygina, E.Y. et al. Synthesis and Complex-Forming Properties of N-Substituted Diazacrown Ethers. Russian Journal of General Chemistry 73, 1919–1924 (2003). https://doi.org/10.1023/B:RUGC.0000025154.24958.66

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  • DOI: https://doi.org/10.1023/B:RUGC.0000025154.24958.66

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