Abstract
Structural and thermodynamic characteristics of adducts of silicon tetrahalides with 2,2'-bipyridine and 1,10-phenanthroline were calculated by the DFT B3LYP method. The enthalpies of sublimation of SiCl4·2,2'-bipyridine, reconstruction energies for donor and acceptor fragments, and energies of Si-N bonds in the complexes under consideration were estimated using the data obtained. These characteristics were compared with similar data for pyridine complexes. The chelate effect on the energy of Si-N bonds upon replacement of pyridine by 2,2'-bipyridine and 1,10-phenanthroline was discussed. The significant reconstruction of the bidentate donor upon the complex formation levels off the chelate effect.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Timoshkin, A.Yu., Sevast'yanova, T.N., Davydova, E.I., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 2003, vol. 73, no. 5, p. 809.
Sevast'yanova, T.N., Misharev, A.D., Anatsko, O.E., and Suvorov, A.V., Zh. Obshch. Khim., 2002, vol. 72, no. 1, p. 64.
Timoshkin, A.Yu., Sevast'yanova, T.N., Davydova, E.I., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 2002, vol. 72, no. 10, p. 1674.
Timoshkin, A.Yu., Sevast'yanova, T.N., Davydova, E.I., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 2002, vol. 72, no. 12, p. 2019.
Sevast'yanova, T.N., Timoshkin, A.Yu., Davydova, E.I., Dubov, O.V., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 2003, vol. 73, no. 1, p. 52.
Adley, A.D., Bird, PH., Frazer, A.R., and Onyszchuk, M., Inorg. Chem., 1972, vol. 11, no. 6, p. 1402.
Gutman, V., Heielmayer, P., and Utvary, K., Monatsh. Chem., 1961, vol. 92, no. 2, p. 322.
Petrosyan, V.P. and Ennan, A.A., Zh. Neorg. Khim., 1976, vol. 23, no. 12, p. 3373.
Ostapchuk, L.V., Gavrilova, L.A., Gel'mbol'dt, V.O., and Ennan, A.A., Zh. Neorg. Khim., 1988, vol. 33, no. 6, p. 1435.
Adley, A.D., Gilson, T., and Onyszchuk, M., Chem. Commun., 1968, no. 14, p. 813.
Gel'mbol'dt, V.O., Petrosyants, S.P., Gavrilova, L.A., and Ennan, A.A., Koord. Khim., 1987, vol. 13, no. 12, p. 1615.
Nguyen, T.Q., Qu, F., Huang, X., and Janzen, A.F., Can. J. Chem., 1992, vol. 70, no. 7, p. 2089.
Beatti, I.R., Gilson, T., Webster, M., and McQuillan, G.P., J. Chem. Soc., 1964, no. 1, p. 238.
Beatti, I.R. and Webster, M., J. Chem. Soc., 1965, no. 6, p. 3672.
Ostapchuk, L.V., Gavrilova, L.A., Gel'mbol'dt, V.O., and Ennan, A.A., Zh. Neorg. Khim., 1988, vol. 33, no. 6, p. 1435.
Gel'mbol'dt, V.O., Zh. Neorg. Khim., 1989, vol. 34, no. 1, p. 239.
Schnell, E. and Wersin, G., Monatsh. Chem., 1961, vol. 92, no. 5, p. 1055.
Wannagat, U., Hensen, K., Petesch, P., and Vielberg, F., Monatsh. Chem., 1967, vol. 98, no. 4, p. 1415.
Anatsko, O.E., Sevast'yanova, T.N., Suvorov, A.V., and Kondrat'ev, Yu.V., Zh. Obshch. Khim., 1999, vol. 69, no. 8, p. 1311.
Sevast'yanova, T.N., Grigor'ev, A.A., German, A.M., Kinysheva, I.I., and Suvorov, A.V., Asbtracts of Papers, XII Vsesoyuznaya konferentsiya po khimicheskoi termodinamike i kalorimetrii (XII All-Union Conf. on Chemical Thermodynamics and Calorimetry), Gor'kii, 1988, part 1, p. 26.
Frisch, M.J., Trucks, G.W., Schlegel, H.B., Gill, P.M.W., Johnson, B.G., Robb, M.A., Cheeseman, J.R., Keith, T., Petersson, G.A., Montgomery, J.A., Raghavachari, K., Al-Laham, M.A., Zakrzewski, V.G., Ortiz, J.V., Forestman, J.B., Cioslowski, J., Stefanov, B.B., Nanayakkara, A., Challacombe, M., Peng, C.Y., Ayala, P.Y., Chen, W., Wong, M.W., Andres, J.L., Replogle, E.S., Gomperts, R., Martin, R.L., Fox, D.J., Binkley, J.S., Defrees, D.J., Barker, J., Stewart, J.P., Head-Gordon, M., Gonzalez, C., and Pople, J.A., GAUSSIAN 94. Rev. C.3, Pittsburgh: Gaussian, 1995.
Becke, A.D., J. Chem. Phys., 1993, vol. 98, no. 7, p. 5648.
Lee, C., Yang, W., and Parr, R.G., Phys. Rev. (B), 1988, vol. 37, no. 2, p. 785.
Modern Theoretical Chemistry, Schaefer, H.F., Ed., New York: Plenum, 1976, vol. 3, p. 1.
Schafer, A., Horn H., and Ahlrichs, R., J. Chem. Phys., 1992, vol. 97, no. 4, p. 2571.
Timoshkin, A.Yu., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 1999, vol. 69, no. 8, p. 1250.
Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Concise Chemical Handbook), St. Petersburg: Khimiya, 1994. RUSSIAN JOURNAL OF GENERAL CHEMISTRY Vol. 73 No. 11 2003 1750 DAVYDOVA et al.
Airodi, C., Silva, M.L.C.P., and Chagas, A.P., J. Chem. Soc., Dalton Trans., 1986, no. 9, p. 1913.
Sevast'yanova, T.N., Vestn. Sankt-Peterb. Gos. Univ., Ser. 4, 1994, no. 2, p. 86.
Timoshkin, A.Yu., Suvorov, A.V., and Schaefer, H.F., Zh. Obshch. Khim., 1998, vol. 68, no. 7, p. 1138.
Dyatlova, N.M., Temkina, V.Ya., and Popov, K.I., Kompleksony i kompleksonaty metallov (Complexones and Metal Complexonates), Moscow: Khimiya, 1988.
Yatsimirskii, K.B., Ross. Khim. Zh., 1996, vol. 40, nos. 4-5, p. 7.
Kukushkin, Yu.N., Khimiya koordinatsionnykh soedinenii (Chemistry of Coordination Compounds), Moscow: Vysshaya Shkola, 1985.
Bain, V.A., Killean, R.C.G., and Webster, M., Acta Crystallogr., Sect. B, 1969, vol. 25, no. 1, p. 156.
Bechstein, O., Ziemer, B., Hass, D., Trojanov, S.I., Rybakov, V.B., and Maso, G.N., Z. Anorg. Allg. Chem., 1990, vol. 582, no. 3, p. 211.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Davydova, E.I., Timoshkin, A.Y., Sevast'yanova, T.N. et al. Quantum-Chemical Study of Adducts of Silicon Halides with Nitrogen-Containing Donors: V. Adducts with 2,2'-Bipyridine and 1,10-Phenanthroline. Russian Journal of General Chemistry 73, 1742–1750 (2003). https://doi.org/10.1023/B:RUGC.0000018651.55510.95
Issue Date:
DOI: https://doi.org/10.1023/B:RUGC.0000018651.55510.95