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Reaction of Phenylurea and N-Trimethylsilyl-N'-phenylurea with Vanadocene and N-Bromosuccinimide

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Abstract

Phenylurea and N-trimethylsilyl-N'-phenylurea react with vanadocene (Cp2V) in toluene to give N-(η5-cyclopentadienyl)vanadio-N'-phenylurea as a major product and Cp2VN = C = O and aniline as byproducts. The reaction of N-trimethylsilyl-N'-phenylurea with N-bromosuccinimide in THF produces, instead of expected N-phenylureidosuccinimide and bromotrimethylsilane, succinimide and N-(p-bromophenyl)-N-trimethylsilylurea which hydrolyzes to form (p-bromophenyl)urea.

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Authors and Affiliations

  1. Nizhny Novgorod State Medical Academy, Nizhny Novgorod, Russia

    A. S. Gordetsov, S. V. Zimina, N. V. Kulagina, E. M. Moseeva, Yu. A. Kurskii & M. A. Lopatin

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  1. A. S. Gordetsov
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  2. S. V. Zimina
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  3. N. V. Kulagina
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  4. E. M. Moseeva
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  5. Yu. A. Kurskii
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  6. M. A. Lopatin
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Gordetsov, A.S., Zimina, S.V., Kulagina, N.V. et al. Reaction of Phenylurea and N-Trimethylsilyl-N'-phenylurea with Vanadocene and N-Bromosuccinimide. Russian Journal of General Chemistry 73, 1557–1560 (2003). https://doi.org/10.1023/B:RUGC.0000016022.68917.bd

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  • DOI: https://doi.org/10.1023/B:RUGC.0000016022.68917.bd

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