Abstract
A series of 12- and 18-membered macrocycloethynes and macrocyclosilethenesilethynes, containing peripheral methyl and phenyl groups was prepared by organomagnesium sysnthesis under conditions of high dilution. One of these compounds contains an endocyclic 1,4-phenylene bridge.
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Yarosh, O.G., Zhilitskaya, L.V., Yarosh, N.K. et al. Highly Unsaturated Macrocyclic Silahydrocarbons Containing Exocyclic Phenyl Groups. Russian Journal of General Chemistry 73, 1552–1554 (2003). https://doi.org/10.1023/B:RUGC.0000016020.37433.f6
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DOI: https://doi.org/10.1023/B:RUGC.0000016020.37433.f6