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Effect of Temperature on Reversible and Irreversible Processes during Lithium Intercalation in Graphite

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Abstract

Effect of temperature on reversible and irreversible processes during lithium intercalation in graphite from 1 M LiClO4 solution in PC–DME is studied by galvanostatic cycling, cyclic voltammetry, and impedance spectroscopy. Reducing temperature diminishes both reversible and irreversible capacities. Conditions for the passive-film formation on graphite are discussed. If several first cycles are run at a negative temperature, the overall charge spent irreversibly decreases if the temperature is then elevated. The lower the initial-cycling temperature, the smaller the overall irreversible capacity.

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  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    T. L. Kulova

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  1. T. L. Kulova
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Kulova, T.L. Effect of Temperature on Reversible and Irreversible Processes during Lithium Intercalation in Graphite. Russian Journal of Electrochemistry 40, 1052–1059 (2004). https://doi.org/10.1023/B:RUEL.0000046490.73990.c3

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  • DOI: https://doi.org/10.1023/B:RUEL.0000046490.73990.c3

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