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Measuring Transport Numbers for Lithium Isotopes in the Li3AlN2 Solid Electrolyte

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Abstract

Transport numbers of the 6Li and 7Li ions in solid electrolyte Li3AlN2 are estimated by passing a constant current and measuring their concentration distribution at 300°C. Up to [6Li] = 50–55 at. %, the 7Li ions are more mobile.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    M. Yu. Bogomolov, V. P. Obrosov, N. N. Batalov & A. A. Surin

  2. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, ul, Pervomaiskaya 91, 620219, Russia

    V. T. Surikov

Authors
  1. M. Yu. Bogomolov
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  2. V. P. Obrosov
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  3. N. N. Batalov
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  4. A. A. Surin
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  5. V. T. Surikov
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Bogomolov, M.Y., Obrosov, V.P., Batalov, N.N. et al. Measuring Transport Numbers for Lithium Isotopes in the Li3AlN2 Solid Electrolyte. Russian Journal of Electrochemistry 40, 670–673 (2004). https://doi.org/10.1023/B:RUEL.0000032020.99752.a1

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  • DOI: https://doi.org/10.1023/B:RUEL.0000032020.99752.a1

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