Skip to main content
SpringerLink
Log in

Methods for Optimizing Properties of Polymer Electrolytes Intended for Lithium Batteries

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

New plasticized polymer electrolytes, based on chlorinated derivatives of polyvinyl chloride, are studied by infrared and impedance spectroscopy. Morphological and electrochemical properties of the electrolytes depend on the nature of the lithium salt and liquid plasticizer and on the technology. Galvanostatic cycling data for lithium batteries based on Li-LiMn2O4 and Li-V6O13 and these electrolytes are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Choe, H.S., Giaccai, J., Alamgir, M., and Abraham, K.M., Electrohim. Acta, 1995, vol. 40, p. 2289.

    Google Scholar 

  2. Yang, C.R., Pern, J.T., Wang, Y.Y., and Wan, C.C., J. Power Sources, 1996, vol. 62, p. 92.

    Google Scholar 

  3. Appetecchi, G.B., Croce, F., and Scrosati, B., Electrochim. Acta, 1995, vol. 40, p. 991.

    Google Scholar 

  4. Alamgir, M. and Abraham, K.M., J. Electrochem. Soc., 1993, vol. 140, p. L96.

    Google Scholar 

  5. Abraham, K.M. and Jiang, Z., J. Electrochem. Soc., 1997, vol. 144, p. L136.

    Google Scholar 

  6. Appetecchi, G.B., Scaccia, S., and Passerini, S., J. Electrochem. Soc., 2000, vol. 147, p. 4448.

    Google Scholar 

  7. Muniyandi, N., Kalaiselvi, N., Periyasamy, P., Thirunakaran, R., Ramesh babu, B., Gopukumar, S., Premkumar, T., Renganathan, N.G., and Raghavan, M., J. Power Sources, 2001, vol. 96, p. 14.

    Google Scholar 

  8. Jarvis, C.R., Macklin, W.J., Macklin, A.J., Mattingley, N.J., and Kronfli, E., J. Power Sources, 2001, vol. 97-98, p. 664.

    Google Scholar 

  9. Travas-Sejdic, J., Steiner, R., Desilvestro, J., and Pickering, P., Electrohim. Acta, 2001, vol. 46, p. 1461.

    Google Scholar 

  10. Alamgir, M. and Abraham, K.M., US Patent 5252413, 1993.

  11. Shapoval, G.S., Tomilov, F.P., Pud, A.A., and Batsalova, K.V., Vysokomolek. Soed. Ser. A, 1987, vol. 29, p. 1424.

    Google Scholar 

  12. Shapoval, G.S., Kontsur, Yu.V., and Pud, A.A., Elektrokhimiya, 1996, vol. 32, p. 142.

    Google Scholar 

  13. Zil'berman, E.N., Sintez i svoistva polivinilkhlorida (Polyvinyl Chloride: Synthesis and Properties), Moscow: Khimiya, 1968.

    Google Scholar 

  14. Choi, N.-S. and Park, J.-K., Electrohim. Acta, 2001, vol. 46, p. 1453.

    Google Scholar 

  15. Fredriksen, O. and Crowo, J.A., Macromol. Chem. Phys., 1967, vol. 100, p. 231.

    Google Scholar 

  16. Shembel, E.M., Chervakov, O.V., Neduzhko, L.I., Maksyuta, I.M., Polischyk, Yu.V., Reisner, D.E., Novak, P., and Meshri, D., J. Power Sources, 2001, vol. 4338, p. 20.

    Google Scholar 

  17. Shembel, E., Chervakov, O., and Novak, P., US Patent Application 2003/0031933, 2003.

  18. Seipold, O., Chem. Tech., 1953, vol. 5, p. 469.

    Google Scholar 

  19. Shin, T., Tadaoki, O., and Tsugio, T., Macromolecules, 1969, vol. 2, p. 277.

    Google Scholar 

  20. Germar, H., Macromol. Chem. Phys., 1965, vol. 86, p. 89.

    Google Scholar 

  21. Krimm, S., Adv. Polym. Sci., 1960, vol. 2, p. 124.

    Google Scholar 

  22. Imrie, C.T., Ingram, M.D., and McHattie, G.S., J. Phys. Chem., 1999, vol. 103, p. 4132.

    Google Scholar 

  23. Percy, M.J. and Wise, L., US Patent Application 243357, 1989.

  24. Klement, J.J., Geil, J. Polym. Sci., Polym. Phys. Ed., 1968, vol. 6, p. 1381.

    Google Scholar 

  25. Shembel, E.M., Chervakov, O.V., Globa, N.I., and Novak, P., US Patent Application 10/126340, 2002.

  26. Kolesnik, Yu.R., Goloshchapov, A.V., Koval', I.V., Teslenko, V.V., and Grekov, A.P., Vysokomolekul. Soed. Ser. A, 1990, vol. 32, p. 2006.

    Google Scholar 

  27. Shembel', E.M., Chervakov, O.V., Neduzhko, L.I., and Maksyuta, I.M., Elektrokhimiya, 2000, vol. 36, p. 599.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine

    E. M. Shembel', L. I. Neduzhko, N. I. Globa & O. V. Kolomoets

  2. Ener-1, Suit 770, 500B Cypress Creek Road, Ft, Lauderdale, 33309, Florida, USA

    O. V. Chervakov, E. M. Shembel' & P. Novak

  3. Advanced Research Chemicals, Inc., Katoosa, Oklahoma, USA

    D. Meshri

Authors
  1. O. V. Chervakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. M. Shembel'
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. I. Neduzhko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. I. Globa
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. V. Kolomoets
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. P. Novak
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. D. Meshri
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chervakov, O.V., Shembel', E.M., Neduzhko, L.I. et al. Methods for Optimizing Properties of Polymer Electrolytes Intended for Lithium Batteries. Russian Journal of Electrochemistry 40, 521–529 (2004). https://doi.org/10.1023/B:RUEL.0000027623.77004.b5

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RUEL.0000027623.77004.b5

Search

Navigation