Abstract
The chemical oxidative polymerization of aniline in a heterophase system is studied. In the presence of a solid substrate, the aniline polymerization involves two kinetically and chemically independent processes, namely, the polymerization in the bulk solution and at the substrate surface. The growth of the polyaniline coating at the substrate surface includes three successive processes: interfacial polymerization, adsorptive polymerization, and destruction of the polymer chain. The interfacial oxidative polymerization of diphenylamine and phenothiazine is examined. The yield and chemical structure of polymers is shown to depend on the polymerization conditions.
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REFERENCES
Kanaizidis, M.G., Chem. Eng. News, 1990, p. 36.
MacDiarmid, A.G. and Epstein, A.J., Faraday Discuss. Chem. Soc., 1989, p. 317.
Gronendaal, B.L., Jonas, F., Freitag, D., Pielartzik, H., and Reinolds, J.R., Adv. Mater. (Weinheim, Fed. Repub. Ger.), 2000, vol. 12, p. 481.
Oyama, N. and Ohsaka, T., Synth. Met., 1987, vol. 18, p. 37.
Wessling, B., Chem. Innov., 2001, vol. 31, p. 34.
Hyodo, K., Electrochim. Acta, 1994, vol. 39, p. 265.
Yang, Y. and Heeger, A.J., Nature, 1994, vol. 372, p. 344.
Kilmartin, P.A., Trier, L., and Wright, G.A., Synth. Met., 2002, vol. 131, p. 99.
Karyakin, A.A., Vuki, M., Lukacheva, L.V., Karyakina, E.E., Orlov, A.V., Karpacheva, G.P., and Wang, J., Anal. Chem., 1999, vol. 71, p. 2534.
Cao, Y., Andreata, A., Heeger, A.J., and Smith, P., Polymer, 1989, vol. 30, p. 2305.
Wang, F.-S., Jing, X.-B., Wang, X.-H., and Dong, A.-J., Synth. Met., 1995, vol. 69, p. 93.
Kaiser, A.B., Subramaniam, C.K., Gilberg, P.W., and Wessling, B., Synth. Met., 1995, vol. 69, p. 197.
Cao, Y., Smith, P., and Heeger, A.J., Synth. Met., 1992, vol. 48, p. 91.
Cao, Y., Treacy, G.M., Smith, P., and Heeger, A.J., Appl. Phys. Lett., 1992, vol. 60, p. 2711.
Cao, Y. and Heeger, A.J., Synth. Met., 1992, vol. 52, p. 193.
Cao, Y., Qui, J., and Smith, P., Synth. Met., 1995, vol. 69, p. 187.
Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.
Orlov, A.V., Kiseleva, S.G., Yurchenko, O.Yu., and Karpacheva, G.P., Vysokomol. Soedin., Ser. A, 2000, vol. 42, p. 2089.
Orlov, A.V., Kiseleva, S.G., Karpacheva, G.P., Teplyakov, V.V., Syrtsova, D.A., Starannikova, L.E., and Lebedeva, T.L., J. Appl. Polym. Sci., 2003, vol. 88, p. 1379.
Tzou, J. and Gregory, R.V., Synth. Met., 1992, vol. 47, p. 267.
Furukava, Y., Ueda, F., Hyodo, Y., Harada, I., Nakajima, T., and Kawagoe, T., Macromolecules, 1988, vol. 21, p. 1297.
Harada, I., Furukava, Y., and Ueda, F., Synth. Met., 1989, vol. 29, p. 303.
Chang, J.S. and MacDiarmid, A.G., Synth. Met., 1986, vol. 13, p. 193.
Maremkulova, S.Zh., Bondarenko, G.N., and Orlov, A.V., Materialy Vseross. nauch. konf. studentov, aspirantov, molodykh uchenykh “Perspektiva 2002” (Proc. All-Russia Sci. Conf. of Students, Post Graduates, and Young Scientists), Nal'chik: Kabardino-Balkar. Gos. Univ., 2002, p. 195.
Orlov, A.V., Yurchenko, O.Yu., Kiseleva, S.G., Razuvaeva, V.S., and Karpacheva, G.P., Vysokomol. Soedin., Ser. A, 2001, vol. 43, p. 552.
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Karpacheva, G.P., Orlov, A.V., Kiseleva, S.G. et al. New Approaches to Synthesizing Electroactive Polymers. Russian Journal of Electrochemistry 40, 305–310 (2004). https://doi.org/10.1023/B:RUEL.0000019669.35766.97
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DOI: https://doi.org/10.1023/B:RUEL.0000019669.35766.97