Abstract
A template oxidative polymerization of aniline in aqueous solutions containing poly-(2-acrylamido-2-methyl-1-propanesulfonic acid) and ammonium persulfate yields a polyaniline complex with the polyacid soluble in water. According to the data of spectral measurements, the process of polymerization is of a pronounced autocatalytic nature. The consequences of this are both the formation of a nonuniform distribution of oxidized and nonoxidized fragments of the polymer chain and the formation of a macroscopic scale of redox nonuniformities in the reaction volume during the process of polymerization. The spectra of absorption of the polyaniline/polyacid films on transparent glass electrodes with a conductive layer of SnO2 and the data of potentiodynamic measurements in the potential region 0–1.0 V (Ag/AgCl) are typical for polyaniline with moderate electroconduction.
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REFERENCES
Handbook of Conducting Polymers, Scotheim, T.A., Ed., New York: Marcel Dekker, 1998, p. 94.
Sun, L. and Yang, S.C., Proc. Mat. Res. Soc. Symp., 1994, vol. 328, p. 167.
Sun, L., Yang, S.C., and Liu, L.-M., Proc. Mat. Res. Soc. Symp., 1994, vol. 328, p. 209.
Sun, L., Liu, L.-M., Clark, R., and Yang, S.C., Synth. Met., 1997, vol. 84, p. 67.
Samuelson, L., Liu, W., Nagarajan, R., Kumar, J., Bruno, F.F., Cholli, A., and Tripathy, S., Synth. Met., 2001, vol. 119, p. 271.
Liu, W., Cholli, A.L., Nagarajan, R., Kumar, J., Tripathy, S., Bruno, F.F., and Samuelson, L., J. Am. Chem. Soc., 1999, vol. 121, p. 11345.
Liu, W., Kumar, J., Tripathy, S., Senecal, K.J., and Samuelson, L., J. Am. Chem. Soc., 1999, vol. 121, p. 71.
Nagarajan, R., Tripathy, S., Kumar, J., Bruno, F.F., and Samuelson, L., Macromolecules, 2000, vol. 33, p. 9542.
Liu, W., Cholli, A.L., Nagarajan, R., Kumar, J., Tripathy, S., Bruno, F.F., and Samuelson, L., J. Am. Chem. Soc., 1999, vol. 121, p. 11345.
Liu, W., Kumar, J., Tripathy, S., Senecal, K.J., and Samuelson, L., J. Am. Chem. Soc., 1999, vol. 121, p. 71.
Liu, W., Anagnostopoulos, A., Bruno, F.F., Senecal, K., Kumar, J., Tripathy, S., and Samuelson, L., Synth. Met., 1999, vol. 101, p. 738.
Vasil'ev, A.A., Sintez polimernykh nerastvorimykh sul'fokislot (sul'fokislotnykh ionitov) (Synthesis of Insoluble Polymer Sulfo Acids (Sulfoacid Ionites)), Leningrad: Nauka, 1971, p. 300.
Nekrasov, A.A., Ivanov, V.F., and Vannikov, A.V., J. Electroanal. Chem., 2000, vol. 482, p. 11.
Ivanov, V.F., Nekrasov, A.A., Gribkova, O.L., and Vannikov, A.V., Abstracts of Papers, 1997 Fall Meet. Mater. Res. Soc., Boston, USA, 1997, Abstract J-II/P10.
Shimano, J.Y. and MacDiarmid, A.G., Synth. Met., 2001, vol. 123, p. 251.
Lux, F., Polymer, 1994, vol. 35, p. 2915.
Nekrasov, A.A., Ivanov, V.F., Gribkova, O.L., and Vannikov, A.V., Electrochim. Acta, 1999, vol. 44, p. 2317.
Ivanov, V.F., Cheberjako, K.V., Nekrasov, A.A., and Vannikov, A.V., Synth. Met., 2001, vol. 119, p. 375.
Ivanov, V.F., Tcheberiako, K.V., Nekrasov, A.A., and Vannikov, A.V., Proc. SPIE, 2001, vol. 4511, p. 187.
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Ivanov, V.F., Gribkova, O.L., Cheberyako, K.V. et al. Template Synthesis of Polyaniline in the Presence of Poly-(2-acrylamido-2-methyl-1-propanesulfonic Acid). Russian Journal of Electrochemistry 40, 299–304 (2004). https://doi.org/10.1023/B:RUEL.0000019668.68527.cc
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DOI: https://doi.org/10.1023/B:RUEL.0000019668.68527.cc