Abstract
It is shown that no less than four types of metal crystals of size up to a few hundreds micrometers with a fifth order symmetry can be electrodeposited. Experiment shows the crystals to form from two-dimensional nuclei and three-dimensional clusters via a disclination mechanism. Possible ways of relaxation of elastic-strain fields from disclinations in the growing pentagonal crystals are shown.
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REFERENCES
Gamburg, Yu.D., Elektrokhimicheskaya kristallizatsiya metallov i splavov (Electrocrystallization of Metals and Alloys), Moscow: Yanus-K, 1997.
Povetkin, V.V. and Kovenskii, I.M., Struktura elektroliticheskikh pokrytii (The Structure of Electrolytic Coatings), Moscow: Metallurgiya, 1989.
Mamontov, E.A., Kozlov, V.M., and Kurbatova, L.A., Poverkhnost, 1982, vol. 10, p. 128.
Mamontov, E.A., Kozlov, V.M., and Kurbatova, L.A., Elektrokhimiya, 1976, vol. 12, p. 602.
Polukarov, Yu.M. and Gamburg, Yu.D., Elektrokhimiya, 1966, vol. 2, p. 389.
Kovenskii, I.M. and Povetkin, V.V., Metallovedenie pokrytii (Analysis of Metals in Coatings), St. Petersburg: SP Intermet Inzhiniring, 1999.
Pangarov, N.A., Rost kristallov (The Crystal Growth), Moscow: Nauka, 1974, vol. 10, p. 71.
Froment, M. and Mourin, C., J. Microscope, 1968, vol. 7, p. 39.
Gryaznov, V.G., Kaprelov, A.M., and Romanov, A.E., Disklinatsii i rotatsionnaya deformatsiya tverdykh tel (Disclinations and Rotational Deformation of Solids), Leningrad: Leningrad. Gos. Univ., 1986, p. 71.
Vikarchuk, A.A., Volenko, A.P., and Yurchenkova, S.A., Elektrokhimiya, 1991, vol. 27, p. 589.
Likhachev, V.A. and Khairov, R.Yu., Vvedenie v teoriyu disklinatsii (An Introduction to Disclination Theory), Leningrad: Leningrad. Gos. Univ., 1973.
Wit, R., J. Phys. C: Solid State Phys., 1972, vol. 5, p. 529.
Gryaznov, V.G., Heidenreich, I., Kaprelov, A.M., Nepijko, S.A., Romanov, A.E., and Urban, I., Crys. Res. Technol., 1999, vol. 34, p. 1091.
Likhachev, V.A., Volkov, A.E., and Shudegov, V.E., Kontinual'naya teoriya defektov (A Continuum Theory of Defects), Leningrad: Leningrad. Gos. Univ., 1986.
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Vikarchuk, A.A., Volenko, A.P., Gamburg, Y.D. et al. Disclination Nature of Pentagonal Crystals that Form during Copper Electrocrystallization. Russian Journal of Electrochemistry 40, 180–187 (2004). https://doi.org/10.1023/B:RUEL.0000016331.27406.63
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DOI: https://doi.org/10.1023/B:RUEL.0000016331.27406.63