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Effect of Chemisorbed Oxide Layers Modified by Nitrogen and Sulfur Atoms on the Catalytic Properties of Platinum Metal Electrodes: A Quantum-Chemical Approach

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Abstract

Electrocatalytic properties of platinum metal electrodes and their dependence on nitrogen- and sulfur-containing additives to electrolyte are studied by an X αdiscrete variation method. It is shown that rhodium catalysts are the most promising, while iridium is unsuitable for the synthesis of percompounds.

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Authors and Affiliations

  1. Far East State University, ul. Sukhanova 8, Vladivostok, 690600, Russia

    T. B. Emelina & O. L. Shcheka

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  1. T. B. Emelina
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  2. O. L. Shcheka
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Emelina, T.B., Shcheka, O.L. Effect of Chemisorbed Oxide Layers Modified by Nitrogen and Sulfur Atoms on the Catalytic Properties of Platinum Metal Electrodes: A Quantum-Chemical Approach. Russian Journal of Electrochemistry 40, 143–147 (2004). https://doi.org/10.1023/B:RUEL.0000016326.83106.e6

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  • DOI: https://doi.org/10.1023/B:RUEL.0000016326.83106.e6

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