Abstract
Electrochemical reduction of nickel complexes with 2,2′-bipyridyl in the presence of ortho-substituted aromatic bromides or white phosphorus leads to the formation of highly reactive organonickel σ-complexes that are capable of selectively reacting with diverse substrates with the formation of cross-association products. Mechanisms of electrocatalytic processes involving organic halides, chlorophosphines, white phosphorus, and nickel complexes with 2,2′-bipyridyl are studied by the cyclic voltammetry and preparative electrolysis methods. Key intermediates of processes that occur in metallocomplex catalysis are determined.
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Yakhvarov, D.G., Budnikova, Y.G. & Sinyashin, O.G. Organonickel σ-Complexes—Key Intermediates of Electrocatalytic Cycles. Russian Journal of Electrochemistry 39, 1261–1270 (2003). https://doi.org/10.1023/B:RUEL.0000003456.78545.0d
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DOI: https://doi.org/10.1023/B:RUEL.0000003456.78545.0d