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New Complexes of Nickel(II) Containing Macrocyclic Diaminodiiminepiperazine Ligands: Synthesis and Electrochemical Properties

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Abstract

Complexes of Ni(ClO4)2 with 1,4-bis(2-aminobenzyl)piperidine (1) and 1,4-bis(2-amino-4-tertbutyl)piperidine (2) and products of their cyclization with ortho-phthalic aldehyde in methanol [NiL3][ClO4]2 (3) and [NiL4][ClO4]2 (4), respectively, are synthesized. Complexes 1 and 2 can be reduced on a platinum electrode irreversibly. Cyclic complexes 3 and 4 undergo reduction reversibly or quasi-reversibly in two or three stages. The reduction products react with n-BuI or n–BuBr (Bu = butyl) via an inner-sphere mechanism of oxidative attachment, probably, with the formation of the Ni–C bond.

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Authors and Affiliations

  1. Chemical Faculty, Moscow State University, Vorob'evy gory 1, Moscow, 119899, Russia

    R. D. Rakhimov, S. Z. Vatsadze, K. P. Butin & N. V. Zyk

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  1. R. D. Rakhimov
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  2. S. Z. Vatsadze
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  3. K. P. Butin
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  4. N. V. Zyk
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Correspondence to K. P. Butin.

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Rakhimov, R.D., Vatsadze, S.Z., Butin, K.P. et al. New Complexes of Nickel(II) Containing Macrocyclic Diaminodiiminepiperazine Ligands: Synthesis and Electrochemical Properties. Russian Journal of Electrochemistry 39, 1253–1260 (2003). https://doi.org/10.1023/B:RUEL.0000003455.12268.e2

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