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New Layered Polymer [{Mn(H2O)3}2{Re6Se8(CN)6}] · 3.3H2O: Synthesis and Properties

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Abstract

The [{Mn(H2O)3}2{Re6Se8(CN)6}] · 3.3H2O complex was produced on slow evaporation of an aqueous solution containing the salt of a cluster complex K4Re6Se8(CN)6 · 3.5H2O and a 23-fold excess of Mn2+. The cluster complexes [Re6Se8(CN)6]4– are linked in a crystal into the charged coordination layers [{Mn(H2O)3}4{Re6Se8(CN)6}3]4– 2∞ through the Mn2+ cations. The Mn2+ cations are coordinated in a layer by three cyano nitrogen atoms of the cluster complexes; the Mn–N bond lengths are 2.13(4) and 2.21(2) Å. Each [Re6Se8(CN)6]4– anion is bonded to three manganese cations Mn(1). The anions are bonded additionally to the Mn(2) cations disordered over two close positions.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia

    N. G. Naumov, S. B. Artemkina, A. V. Virovets & V. E. Fedorov

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  1. N. G. Naumov
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  2. S. B. Artemkina
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  3. A. V. Virovets
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  4. V. E. Fedorov
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Naumov, N.G., Artemkina, S.B., Virovets, A.V. et al. New Layered Polymer [{Mn(H2O)3}2{Re6Se8(CN)6}] · 3.3H2O: Synthesis and Properties. Russian Journal of Coordination Chemistry 30, 792–799 (2004). https://doi.org/10.1023/B:RUCO.0000047466.28548.48

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  • DOI: https://doi.org/10.1023/B:RUCO.0000047466.28548.48

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