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Complexes of Some 3d-Metal Salts with N,N-Dimethylhydrazide of 4-Nitrobenzoic Acid

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Abstract

The [M(HL)2(H2O)2]X2 complexes were synthesized (M = Mn(II), Co(II), Ni(II), Cu(II), Zn; X = CH3COO–, Cl–, BF4 –) that incorporate bidentately coordinated molecules of N,N-dimethylhydrazide of 4-nitrobenzoic acid (HL). The latter molecules chelate the metal atom through the carbonyl O atom and the N atom of dimethylamino group. The square-planar complexes of Cu and Ni with deprotonated form of a ligand with composition ML2 were also isolated. The synthesized complexes were studied by IR, electronic and EPR spectroscopies, and by cyclic voltammetry.

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Authors and Affiliations

  1. Shevchenko National University, ul. Vladimirskaya 64, Kiev, 01033, Ukraine

    V. Ya. Zub & P. V. Bugaeva

  2. National Technical University, pr. Pobedy 37, Kiev, 03056, Ukraine

    N. G. Strizhakova & Yu. A. Maletin

Authors
  1. V. Ya. Zub
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  2. P. V. Bugaeva
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  3. N. G. Strizhakova
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  4. Yu. A. Maletin
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Zub, V.Y., Bugaeva, P.V., Strizhakova, N.G. et al. Complexes of Some 3d-Metal Salts with N,N-Dimethylhydrazide of 4-Nitrobenzoic Acid. Russian Journal of Coordination Chemistry 30, 747–752 (2004). https://doi.org/10.1023/B:RUCO.0000043902.12955.5e

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  • DOI: https://doi.org/10.1023/B:RUCO.0000043902.12955.5e

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