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Copper(II) Chelate Complex with N′-(2,4-Dichlorophenoxy)acetyl-N,N-Dimethylhydrazine: Crystal and Molecular Structure

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Abstract

X-ray diffraction analysis of the copper(II) chelate complex CuL2 (where L is the deprotonated imid-ol form of N,N-dimethyl-2,4-dichlorophenoxyacetohydrazide (HL)) was performed (3826 reflections, R = 0.039, wR = 0.043). Crystals are monoclinic, a = 8.365(7) Å, b = 23.090(7)Å, c = 12.713(3) Å, β = 95.12(6)°, space group P21/c, Z = 4. The slightly distorted square environment of the copper cation is composed of two N atoms of the dimethylamino groups and two O atoms of the deprotonated imidol groups. Both N and O atoms are located in trans-positions relative to each other. Additional coordination of electron-donor atoms is prevented by methyl groups, in which the C atoms are at a distance of 2.837 to 2.918 Å from the central ion.

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Authors and Affiliations

  1. Vernadsky Crimean National University, Simferopol, Ukraine

    V. F. Shul'gin & N. S. Pevzner

  2. Shevchenko National University, Vladimirskaya ul. 64, Kiev, 01033, Ukraine

    V. Ya. Zub

  3. The Ukraine National Technical University, pr. Pobedy, 37, Kiev, 03056, Ukraine

    N. G. Strizhakova & Yu. A. Maletin

Authors
  1. V. F. Shul'gin
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  2. N. S. Pevzner
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  3. V. Ya. Zub
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  4. N. G. Strizhakova
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  5. Yu. A. Maletin
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Shul'gin, V.F., Pevzner, N.S., Zub, V.Y. et al. Copper(II) Chelate Complex with N′-(2,4-Dichlorophenoxy)acetyl-N,N-Dimethylhydrazine: Crystal and Molecular Structure. Russian Journal of Coordination Chemistry 30, 723–726 (2004). https://doi.org/10.1023/B:RUCO.0000043898.36993.d4

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  • DOI: https://doi.org/10.1023/B:RUCO.0000043898.36993.d4

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