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Crystal Structure and Thermal Stability of Ag3(CHF2COO)3(H2O)2

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Abstract

X-ray diffraction analysis of [Ag3(CHF2COO)3(H2O)2] revealed that its crystals are orthorhombic: space group Cmca, a = 13.809(4) Å, b = 15.975(2) Å, c = 12.244(2) Å, Z = 8. The thermogravimetric analysis showed that under the atmosphere of N2 and at 101.3 kPa, silver difluoroacetate melts at 488 K; the thermal decomposition reaction occurs in the interval 493–548 K with the formation of Ag. Under the mass-spectral experiment conditions at 521 K, two processes occur simultaneously, namely, evaporation and decomposition. The following ions were detected in the mass-spectrum of silver difluoroacetate: Ag2L+, Ag2R+, Ag2F+, Ag2O+, Ag2 +, Ag+, LH+, RCO+, R+ (L = CHF2COO, R = CHF2).

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REFERENCES

  1. Sheldrick G.M., SHELXS97, SHELXL97, Göttingen (Germany): Univ. of Göttingen, 1997.

  2. International Tables for X-Ray Crystallography, Ibers, J.A. and Hamilton, W.C., Eds., Birmingham: Kynoch Press, 1974. vol. 4, p. 278.

    Google Scholar 

  3. Coggon, P. and McPhail, A.T., J. Chem. Soc., Chem. Commun., 1972, no. 2, p. 91.

    Google Scholar 

  4. Eriksson, L. and Kritikos, M., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, p. 1508.

    Google Scholar 

  5. Karpova, E.V., Boltalin, A.I., Korenev, Yu.M., et al., Koord. Khim., 2000, vol. 26, no. 7, p. 489.

    Google Scholar 

  6. Karpova, E.V., Boltalin, A.I., Zakharov, M.A., et al., Z. Anorg. Allg. Chem., 1998, vol. 624, no. 4, p. 741.

    Google Scholar 

  7. Karpova, E.V., Boltalin, A.I., Korenev, Yu.M, and Troy-anov, S.I., Koord. Khim., 2000, vol. 26, no. 5, p. 384.

    Google Scholar 

  8. Smith, G., Reddy, A.N., Byriel, K.A., and Kennard, C.H.L., J. Chem. Soc., Dalton Trans., 1995, no. 22, p. 3565.

    Google Scholar 

  9. Wu, D.-D. and Mak, T.C.W., J. Chem. Soc., Dalton Trans., 1995, no. 16, p. 2671.

    Google Scholar 

  10. Smith, G., Reddy, A.N., Byriel, K.A., and Kennard, C.H.L., Polyhedron, 1994, vol. 13, p. 3135.

    Google Scholar 

  11. Karpova, E.V., Boltalin, A.I., Korenev, Yu.M., et al., Koord. Khim., 2001, vol. 27, no. 4, p. 311.

    Google Scholar 

  12. Paramonov, S.E., Mychlo, E.V., Troyanov, S.I., and Kuz'mina, N.P., Zh. Neorg. Khim., 2000, vol. 45, no. 12, p. 2003.

    Google Scholar 

  13. Karpova, E.V., Boltalin, A.I., Korenev, Yu.M., et al., Koord. Khim., 1999, vol. 25, no. 1, p. 70.

    Google Scholar 

  14. Karpova, E.V., Boltalin, A.I., Korenev, Yu.M., et al., Zh. Neorg. Khim., 1996, vol. 41, no. 7, p. 1185.

    Google Scholar 

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Authors and Affiliations

  1. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    A. I. Boltalin, S. A. Kas'yanov, E. V. Karpova & S. I. Troyanov

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  1. A. I. Boltalin
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  2. S. A. Kas'yanov
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  3. E. V. Karpova
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  4. S. I. Troyanov
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Boltalin, A.I., Kas'yanov, S.A., Karpova, E.V. et al. Crystal Structure and Thermal Stability of Ag3(CHF2COO)3(H2O)2 . Russian Journal of Coordination Chemistry 30, 692–697 (2004). https://doi.org/10.1023/B:RUCO.0000043892.10551.fa

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  • DOI: https://doi.org/10.1023/B:RUCO.0000043892.10551.fa

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