Abstract
Reactions of vanadium and molybdenum with 3,5-di-tert-butyl-ortho-benzoquinone (I) in coordinating solvents were studied, and the reaction intermediates were detected from EPR spectra. The product of vanadium reaction with I in pyridine was isolated. The oxidation of V and Mo with quinone I was shown to follow the Langmuir–Hinshelwood scheme involving the reagent adsorption on reaction centers of different nature. The kinetic parameters of reactions were determined, and the equilibrium constants and the enthalpy and entropy of adsorption of quinone I and DMSO on the metal surface were calculated.
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Maslennikov, S.V., Aivaz'yan, I.A., Fukin, G.K. et al. Reactions of V and Mo with 3,5-Di-tert-butyl-1,2-benzoquinone in Coordinating Solvents. Russian Journal of Coordination Chemistry 30, 628–633 (2004). https://doi.org/10.1023/B:RUCO.0000040722.76821.86
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DOI: https://doi.org/10.1023/B:RUCO.0000040722.76821.86